Variable-temperature and variable-pressure studies of small-molecule organic crystals

被引：47

作者：

Boldyreva, EV ^{[1
]}

Drebushchak, TN

Shakhtshneider, TP

Sowa, H

Ahsbahs, H

Goryainov, SV

Ivashevskaya, SN

Kolesnik, EN

Drebushchak, VA

Burgina, EB

机构：

[1] Novosibirsk State Univ, REC Mol Design & Ecologically Safe Technol 008, Pirogova 2, Novosibirsk 630090, Russia

[2] RAS, SB, Inst Solid State Chem, Novosibirsk, Russia

[3] Univ Marburg, D-35032 Marburg, Germany

[4] RAS, SB, Inst Mineral & Petrog, Novosibirsk, Russia

[5] RAS, Karelian Sci Ctr, Inst Geol, Petrozavodsk, Russia

[6] RAS, SB, Boreskov Inst Catalysis, Novosibirsk, Russia

来源：

ARKIVOC | 2004年

关键词：

hydrogen bonds; high pressure; amino acids; polymorphs; phase transitions;

D O I：

10.3998/ark.5550190.0005.c10

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Several examples of the comparative variable- temperature and variable- pressure studies of the small- molecule organic crystals are discussed. Selected systems represent the crystals with nonspherical flexible molecules / molecular fragments and with different types of intermolecular interactions, ranging from van der Waals interactions to hydrogen bonds of various types ( OH ... O, NH ... OH, NH ... O= C). A special attention is payed to the studies of solid drugs ( polymorphs of paracetamol), amino acids ( polymorphs of glycine, L- serine, D, L- serine), and dipeptides ( glycilglycine and glycilglycine hydrate) by structural, spectroscopic and calorimetric techniques. The anisotropy of structural distortion within the range of stability of the same phase, as well as the phase transitions induced by changes in temperature or pressure are discussed.

引用

页码：128 / 155

页数：28

共 83 条

[1] [Anonymous], 1995, ANGEW CHEM, V107, P2541
[2] BENEDETT.E, 1973, GAZZ CHIM ITAL, V103, P555
[3] Bernstein J., 2002, IUCR MONOGRAPHS CRYS, V14
[4] The prediction, morphology, and mechanical properties of the polymorphs of paracetamol
Beyer, T
Day, GM
Price, SL
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (21) : 5086 - 5094
[5] Experimental and ab initio MO studies on the IR spectra and structure of 4-hydroxyacetanilide (paracetamol), its oxyanion and dianion
Binev, IG
Vassileva-Boyadjieva, P
Binev, YI
[J]. JOURNAL OF MOLECULAR STRUCTURE, 1998, 447 (03) : 235 - 246
[6] Distortion of crystal structures of some Co-III ammine complexes .2. Distortion of crystal structures of [Co(NH3)(5)NO2]X-2 (X=Cl, Br) on cooling
Boldyreva, E
Kivikoski, J
Howard, JAK
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1997, 53 : 405 - 414
[7] Distortion of crystal structures of some Co-III ammine complexes .1. Distortion of crystal structure of [Co(NH3)(5)NO2]Cl(NO3) on cooling
Boldyreva, E
Kivikoski, J
Howard, JAK
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1997, 53 : 394 - 404
[8] Distortion of crystal structures of some CoIII ammine complexes.: III.: Distortion of crystal structure of [Co(NH3)5NO2]Cl2 at hydrostatic pressures up to 3.5 GPa
Boldyreva, EV
Naumov, DY
Ahsbahs, H
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1998, 54 : 798 - 808
[9] High pressure and supramolecular systems
Boldyreva, EV
[J]. RUSSIAN CHEMICAL BULLETIN, 2004, 53 (07) : 1369 - 1378
[10] Boldyreva EV, 2004, NATO SCI SER II-MATH, V140, P495

← 1 2 3 4 5 6 7 8 9 →