Attempted synthesis of Fjord-region containing polycyclic fluoranthenes reveals a steric-driven double Wagner-Meerwein rearrangement

被引：10
作者：
Cho, BP
Zhou, L
机构：
[1] Department of Medicinal Chemistry, University of Rhode Island, Kingston
来源：
TETRAHEDRON LETTERS | 1996年 / 37卷 / 10期
关键词：
D O I：
10.1016/0040-4039(96)00065-2
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A double Wagner-Meerwein rearrangement takes place commonly in the synthesis of sterically hindered polycyclic fluoranthenes via cyclodehydration reactions and the extent of intramolecular steric crowding within the initially formed tertiary cationic intermediate controls the equilibrium between the expected and the rearranged product.
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页码：1535 / 1538
页数：4
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