Synthesis and Properties of Hydrido(selenolato)platinum(II) Complexes Bearing Chelating Phosphine Ligands

被引：8
作者：
Nakata, Norio [1 ]
Yoshino, Tomoharu [1 ]
Ishii, Akihiko [1 ]
机构：
[1] Saitama Univ, Dept Chem, Grad Sch Sci & Engn, Sakura Ku, Saitama 3388570, Japan
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2010年 / 185卷 / 5-6期
关键词：
Hydrido complex; platinum; selenaplatinacycle; selenium; selenol; X-ray crystallography; BOND ADDITION; SE-H; C-S; SELENOSELENINATE; HYDROLYSIS; PALLADIUM; ACID;
D O I：
10.1080/10426501003772078
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reactions of an overcrowded selenol, TripSeH (1, Trip = 9-triptycyl) with [PtCl2L] (L = dppe, dppf), in the presence of NaBH4 afforded the corresponding hydrido(selenolato) platinum(II) complexes [PtH(SeTrip)(L)] [2 (L = dppe), 3 (L = dppf)]. Complexes 2 and 3 were fully characterized by NMR and IR spectroscopies, and their molecular structures were determined by X-ray crystallography. Thermal reaction of 2 or treatment of 2 with an excess amount of HBF4 produced five-membered selenaplatinacycle [Pt(2-C,Se-Trip)(dppe)] 4 in moderate yields.
引用
收藏
页码：992 / 999
页数：8
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