Assembly of a 3D nanoporous framework [Cu6(OH)4(tib)8]n8+ from Cu(II) and the flexible tripodal ligand tib

被引：35

作者：

Liu, HK ^{[1
]}

Tan, HY

Cai, JW

Zhou, ZY

Chan, ASC

Liao, S

Xiao, W

Zhang, HX

Yu, XL

Kang, BS

机构：

[1] Zhongshan Univ, Sch Chem & Chem Engn, Guangzhou 510275, Guangdong, Peoples R China

[2] Zhongshan Univ, Instrumentat Anal & Res Ctr, Guangzhou 510275, Guangdong, Peoples R China

[3] Hong Kong Polytech Univ, Open Lab Chiral Technol, Kowloon, Hong Kong, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 11期

关键词：

D O I：

10.1039/b100325i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structural characterization of a 3D nanoporous complex {[Cu-6(tib)(8)(OH)(4)](OH)(8). 22H(2)O . 4MeOH}(n) 1 [tib = 1,3,5-tris- (imidazol-1-ylmethyl)benzene] assembled from the tripodal ligand tib and Cu(MeCO2)(2) shows that pi-pi interactions resulting from the novel T-shaped conformation of the ligand are the key trigger for the construction of the backbone of a framework with channels of size 12.00 x 18.91 and 10.30 x 13.66 Angstrom.

引用

页码：1008 / 1009

页数：2

共 13 条

[1]

Abrahams BF, 1999, ANGEW CHEM INT EDIT, V38, P1475, DOI 10.1002/(SICI)1521-3773(19990517)38:10<1475::AID-ANIE1475>3.0.CO

[2]

2-3

[3] A cubic (3,4)-connected net with large cavities in solvated [Cu-3(tpt)(4)](ClO4)(3) (tpt=2,4,6-tri(4-pyridyl)-1,3,5-triazine) [J].

Abrahams, BF ;

Batten, SR ;

Hamit, H ;

Hoskins, BF ;

Robson, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (15) :1690-1692

[4] An alternative to interpenetration whereby nets with large windows may achieve satisfactory space filling [J].

Batten, SR ;

Hoskins, BF ;

Moubaraki, B ;

Murray, KS ;

Robson, R .

CHEMICAL COMMUNICATIONS, 2000, (13) :1095-1096

[5] 2 INTERPENETRATING 3D NETWORKS WHICH GENERATE SPACIOUS SEALED-OFF COMPARTMENTS ENCLOSING OF THE ORDER OF 20 SOLVENT MOLECULES IN THE STRUCTURES OF ZN(CN)(NO3)(TPT)(2/3)CENTER-DOT-SOLV (TPT=2,4,6-TRI(4-PYRIDYL)-1,3,5-TRIAZINE, SOLV=SIMILAR-TO-3/4C(2)H(2)CL(4)CENTER-DOT-3/4CH(3)OH OR SIMILAR-TO-3/2CHCL(3)CENTER-DOT-1/3CH(3)OH) [J].

BATTEN, SR ;

HOSKINS, BF ;

ROBSON, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (19) :5385-5386

[6] Exchange properties of the three-dimensional coordination compound 1,3,5-tris(4-ethynylbenzonitrile)benzene center dot AgO3SCF3 [J].

Gardner, GB ;

Kiang, YH ;

Lee, S ;

Asgaonkar, A ;

Venkataraman, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (29) :6946-6953

[7] SPONTANEOUS ASSEMBLY OF A HINGED COORDINATION NETWORK [J].

GARDNER, GB ;

VENKATARAMAN, D ;

MOORE, JS ;

LEE, S .

NATURE, 1995, 374 (6525) :792-795

[8]

Hagrman PJ, 1999, ANGEW CHEM INT EDIT, V38, P2639

[9] Nanoporous and mesoporous organic structures: new openings for materials research [J].

Langley, PJ ;

Hulliger, J .

CHEMICAL SOCIETY REVIEWS, 1999, 28 (05) :279-291

[10] A two-dimensional network constructed via 72-membered heart-shaped macrocycles, a copper(II) complex with 1,3,5-tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene and diethylenetriamine ligands [J].

Liu, HK ;

Sun, WY ;

Zhu, HL ;

Yu, KB ;

Tang, WX .

INORGANICA CHIMICA ACTA, 1999, 295 (02) :129-135

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