Catalytic coupling of ethylene and internal olefins by dicationic palladium(II) and platinum(II) complexes: Switching from hydrovinylation to cyclopropane ring formation

被引：48

作者：

Cucciolito, ME ^{[1
]}

D'Amora, A ^{[1
]}

Vitagliano, A ^{[1
]}

机构：

[1] Univ Naples Federico II, Dipartimento Chim, Complesso Univ Monte Sant Angelo, I-80126 Naples, Italy

来源：

ORGANOMETALLICS | 2005年 / 24卷 / 14期

关键词：

D O I：

10.1021/om050397l

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dicationic palladium(II) and platinum(II) complexes [(PNP)M(C2H4)]BF4)(2) (1a, M = Pt; 1b, M = Pd; PNP = 2,6-bis((diphenylphosphino)methyl)pyridine) and [(PPP)Pt(C2H4)](BF4)(2) (7; PPP = triphos) catalyze a cross-coupling reaction of ethylene with triand tetrasubstituted olefins, which can lead to both hydrovinylation and cyclopropanation products. The product ratio is strongly affected by the choice of the ligand and of the metal, the two limiting cases being la and 7, which selectively give the hydrovinylation and the cyclopropanation products, respectively.

引用

页码：3359 / 3361

页数：3

共 18 条

[11] STABLE ETA-ETHENE AND SIGMA-ETHENE CATIONIC COMPLEXES OF PLATINUM(II) [J].