Charge Neutral [Cu2L2] and [Pd2L2] Metallocycles: Self-Assembly, Aggregation, and Catalysis

被引：12
|
作者：
Kolodziejski, Michal [1 ,2 ]
Brock, Aidan J. [3 ]
Kurpik, Gracjan [1 ,2 ]
Walczak, Anna [1 ,2 ]
Li, Feng [4 ]
Clegg, Jack K. [3 ]
Stefankiewicz, Artur R. [1 ,2 ]
机构：
[1] Adam Mickiewicz Univ, Fac Chem, PL-61614 Poznan, Poland
[2] Adam Mickiewicz Univ, Ctr Adv Technol, PL-61614 Poznan, Poland
[3] Univ Queensland, Sch Chem & Mol Biosci, St Lucia, Qld 4072, Australia
[4] Western Sydney Univ, Sch Sci, Penrith, NSW 2751, Australia
来源：
INORGANIC CHEMISTRY | 2021年 / 60卷 / 13期
基金：
澳大利亚研究理事会;
关键词：
COUPLING REACTIONS; CROSS-COUPLINGS; BETA-DIKETONE; PALLADIUM; COMPLEXES; LIGANDS; CAGES; BROMIDES; IODIDES; ARYL;
D O I：
10.1021/acs.inorgchem.1c00967
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A range of morphologically distinct metallosupramolecular Cu(II) and Pd(II) complexes has been constructed, based on the tritopic ligand 1,1',1 ''-(benzene-1,3,5-triyl)tris(4,4-dimethylpentane-1,3-dione) (H3L). By control of the reaction conditions, it is possible to generate distinct coordination assemblies possessing either macrocyclic or polymeric structures and more importantly distinct activity in catalysis of the Suzuki-Miyaura cross-coupling.
引用
收藏
页码：9673 / 9679
页数：7
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