1H NMR spectra of platinum(II) complexes containing piperidine and another amine

被引：5

作者：

Dinh, NH ^{[1
]}

Da, TT ^{[1
]}

机构：

[1] Hanoi Pedagog Univ, Dept Chem, Hanoi, Vietnam

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2003年 / 56卷 / 08期

关键词：

cis-diaraine platinum(II); H-1; NMR; platinum(II) complexes; piperidine;

D O I：

10.1080/0095897031000114002

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

H-1 NMR spectra of a series of cis-[Pt(Pip)(Am)Cl-2] complexes (Pip=piperidine, Am=another amine) have been recorded and analyzed. Spin-spin splitting patterns of nonequivalent protons H-alpha(a), H-alpha(e), H-beta(a), H-beta(e), H-gamma(a), and H-gamma(e) of piperidine have been designated. The piperidine ring has a chair confirmation with the nitrogen atom bound to the Pt atom in an equatorial manner; the examined complexes have a cis-configuration, with the plane of aromatic an-tine and the piperidine ring perpendicular to the coordination plane of Pt(II).

引用

页码：683 / 689

页数：7

共 14 条

[1]

DA TT, 2001, TAP CHI HOA HOC, V39, P99

[2]

DA TT, 2001, TAP CHI DUOC HOC, V6, P6

[3] Structure, stability, and interconversion barriers of the rotamers of cis-[PtIICl2(quinoline)2] and cis-[PtIICl2(3-bromoquinoline) (quinoline)] from X-ray crystallography, NMR spectroscopy and molecular mechanics evidence [J].