(1SR,2RS,3SR,5SR,6RS)-6-[(Z)-1-Acetoxy-2-phenylethenyl]-3-ethoxy-2-phenylbicyclo[3.1.0]hexan-1-yl acetate

被引：0

作者：

Hu, Wen-Xiang ^{[1
]}

Xu, Gao ^{[1
]}

Wei, Guo-Qiang ^{[1
]}

机构：

[1] Capital Normal Univ, Dept Chem, Beijing 100048, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1107/S1600536811001760

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The molecule of the title compound, C26H28O5, is chiral with five stereogenic centres; however, the centrosymmetric triclinic group gives a racemic crystal. The fused ring system adopta boat conformation in which the cyclopropane ring plane is roughly perpendicular to the styryl group plane, forming a dihedral angle of 74.78 (19)degrees. The dihedral angle between the two benzene rings is 77.24 (6)degrees.

引用

页码：O512 / U1927

页数：11

共 10 条

[1]

[Anonymous], 2008, CRYSTALCLEAR

[2]

Brandenburg K., 1999, DIAMOND

[3] Synthesis of cyclopropane containing natural products [J].

Donaldson, WA .

TETRAHEDRON, 2001, 57 (41) :8589-8627

[4] Conformationally locked carbocyclic nucleosides built on a bicyclo[3.1.0]hexane template with a fixed Southern conformation. Synthesis and antiviral activity [J].

Ezzitouni, A ;

Marquez, VE .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1997, (07) :1073-1078

[5] ASYMMETRIC-SYNTHESIS OF ENANTIOMERICALLY PURE AND DIVERSELY FUNCTIONALIZED CYCLOPROPANES [J].

HANESSIAN, S ;

ANDREOTTI, D ;

GOMTSYAN, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (41) :10393-10394

[6] Au(I)-catalyzed efficient synthesis of functionalized bicyclo[3.2.0]heptanes [J].

Li, Guotao ;

Huang, Xiaogen ;

Zhang, Liming .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (22) :6944-+

[7] Design, synthesis, and pharmacological characterization of (+)-2-aminobicyclo[3.1.0]hexane-2,6-dicarboxylic acid (LY354740): A potent, selective, and orally active group 2 metabotropic glutamate receptor agonist possessing anticonvulsant and anxiolytic properties [J].

Monn, JA ;

Valli, MJ ;

Massey, SM ;

Wright, RA ;

Salhoff, CR ;

Johnson, BG ;

Howe, T ;

Alt, CA ;

Rhodes, GA ;

Robey, RL ;

Griffey, KR ;

Tizzano, JP ;

Kallman, MJ ;

Helton, DR ;

Schoepp, DD .

JOURNAL OF MEDICINAL CHEMISTRY, 1997, 40 (04) :528-537

[8] A short history of SHELX [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

[9] publCIF: software for editing, validating and formatting crystallographic information files [J].

Westrip, Simon P. .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2010, 43 :920-925

[10] Au-containing all-carbon 1,4-dipoles: Generation and [4+2] annulation in the formation of carbo-/heterocycles [J].

Zhang, Guozhu ;

Huang, Xiaogen ;

Li, Guotao ;

Zhang, Liming .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (06) :1814-+

← 1 →