Non-exponential decays in first-order kinetic processes. The case of "Squeezed Exponential"

被引：0
|
作者：
Sworakowski, J. [1 ]
Matczyszyn, K. [1 ]
机构：
[1] Wroclaw Univ Technol, Inst Phys & Theoret Chem, PL-50370 Wroclaw, Poland
来源：
ACTA PHYSICA POLONICA A | 2007年 / 112卷
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D O I：
暂无
中图分类号：
O4 [物理学];
学科分类号：
0702 ;
摘要：
Kinetics of processes, in which the reaction rate increases with conversion, is discussed and illustrated with an example of the chemical reaction of isomerization of an azobenzene derivative in a liquid crystalline matrix. A simple phenomenological model is put forward explaining the effect by dynamic changes of interactions between the reacting species and the matrix.
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页码：S153 / S159
页数：7
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