Oxidative reactions by a palladium-alkyl nitrite system

被引：115

作者：

Uchiumi, S ^{[1
]}

Ataka, K ^{[1
]}

Matsuzaki, T ^{[1
]}

机构：

[1] UBE Ind Ltd, Ube Lab, Yamaguchi 7550067, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 576卷 / 1-2期

关键词：

alkyl nitrite; palladium; dimethyl oxalate; dimethyl carbonate; olefin oxidation;

D O I：

10.1016/S0022-328X(98)01064-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The typical oxidative reactions ((1) dialkyl oxalate synthesis from carbon monoxide, (2) dialkyl carbonate synthesis from carbon monoxide, (3) acetals and ketals synthesis from olefins, and (4) oxidative carbonylation of olefins) catalyzed by palladium in the presence of alkyl nitrites, are described. The mechanistic studies are conducted based on reaction kinetics. In addition, derivation of acetals obtained by olefin oxidation to various useful fine chemicals is also described. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：279 / 289

页数：11

共 75 条

[1] REACTIONS OF PI-ALLYLIC PALLADIUM(II) COMPLEXES OF ACETOACETATE ESTERS WITH PYRIDINE AND ITS DERIVATIVES [J].