Directing the pathway of orthogonal 'click' reactions by modulating copper-catalytic activity

被引：34
作者：
Jia, Zhongfan [1 ]
Bell, Craig A. [1 ]
Monteiro, Michael J. [1 ]
机构：
[1] Univ Queensland, Australian Inst Bioengn & Nanotechnol, Brisbane, Qld 4072, Australia
来源：
CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 14期
关键词：
TRANSFER RADICAL POLYMERIZATION; TERMINAL ALKYNES; VINYL-CHLORIDE; CHEMISTRY; DENDRIMERS; AZIDES; COMPLEXES; EFFICIENT; LIGATION; POLYMERS;
D O I：
10.1039/c0cc05478j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Control of the rates of orthogonal 'click' reactions in one pot allowed the design of highly branched macromolecular architectures. Construction of these architectures via a divergent, convergent or parallel sequence was modulated by the copper catalyst activity. This approach reduced the number of purification and chemical protection steps.
引用
收藏
页码：4165 / 4167
页数：3
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