Nickel-Catalyzed Decarbonylative Silylation, Borylation, and Amination of Arylamides via a Deamidative Reaction Pathway

被引：56
作者：
Lee, Shao-Chi [1 ]
Guo, Lin [1 ]
Yue, Huifeng [1 ]
Liao, Hsuan-Hung [1 ]
Rueping, Magnus [1 ,2 ]
机构：
[1] Rhein Westfal TH Aachen, Inst Organ Chem, Landoltweg 1, D-52074 Aachen, Germany
[2] King Abdullah Univ Sci & Technol, KAUST Catalysis Ctr KCC, Thuwal 239556900, Saudi Arabia
来源：
SYNLETT | 2017年 / 28卷 / 19期
关键词：
nickel catalysis; decarbonylation; amination; silylation; borylation; CROSS-COUPLING REACTIONS; N BOND ACTIVATION; C-H FUNCTIONALIZATION; TRANSITION-METAL-COMPLEXES; ORGANIC HALIDES; ORGANOBORON COMPOUNDS; CLEAVING ALKYLATION; CINNAMIC ANHYDRIDES; ACID-CHLORIDES; SP(3) CARBON;
D O I：
10.1055/s-0036-1591495
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A nickel-catalyzed decarbonylative silylation, borylation, and amination of amides has been developed. This new methodology allows the direct interconversion of amides to arylsilanes, arylboronates, and arylamines and enables a facile route for carbon-heteroatom bond formations in a straightforward and mild fashion.
引用
收藏
页码：2594 / 2598
页数：5
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