On the Hellmann-Feynman theorem and the corrections to the energy in the Rayleigh-Schrodinger perturbation theory

被引:1
|
作者
Almeida, R [1 ]
Riega, HDY [1 ]
Morales, DA [1 ]
机构
[1] Univ Los Andes, Dept Quim, Merida 5101, Venezuela
关键词
Hellmann-Feynman theorem; perturbation theory;
D O I
10.1023/A:1018808830396
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this work we present an alternative method, based on the Hellmann-Feynman theorem, to generate energy corrections within the standard Rayleigh-Schrodinger perturbation theory. As a result, compact expressions for the corrections to the energy at different orders are obtained. We also review a method that allows us to calculate the corrections to the wave function needed in the energy calculations. Finally, our results are compared with those obtained by other authors by a different technique.
引用
收藏
页码:201 / 206
页数:6
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