Poly[bis(N-methylformamide)tetra-μ-thiocyanato-manganese(II)-mercury(II)]

被引：5

作者：

Wang, XQ ^{[1
]}

Yu, WT ^{[1
]}

Xu, D ^{[1
]}

Zhang, GH ^{[1
]}

Geng, YL ^{[1
]}

机构：

[1] Shandong Univ, Inst Crystal Mat, State Key Lab Crystal Mat, Jinan 250100, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2005年 / 61卷

关键词：

D O I：

10.1107/S0108270105010814

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title complex, [MnHg(NCS)(4)(C2H5NO)(2)](n), consists of slightly distorted MnN4O2 octahedra and HgS4 tetrahedra. Each Mn-II cation is bound to four N atoms of the NCS groups and two O atoms of the N-methylformamide (NMF) ligands in a cis configuration. Each Hg-II cation is coordinated to four S atoms of NCS groups. Each pair of Mn-II and Hg-II cations is connected by an - NCS - bridge, forming an infinite three-dimensional - Mn - NCS - Hg - network.

引用

页码：M278 / M280

页数：3

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