Long-Range Chiral Induction by a Fully Noncovalent Approach in Supramolecular Porphyrin-Calixarene Assemblies

被引：17

作者：

Gaeta, Massimiliano ^{[1
]}

Sortino, Giuseppe ^{[1
]}

Randazzo, Rosalba ^{[1
]}

Pisagatti, Ilenia ^{[2
]}

Notti, Anna ^{[2
]}

Fragala, Maria Elena ^{[1
]}

Parisi, Melchiorre F. ^{[2
]}

D'Urso, Alessandro ^{[1
]}

Purrello, Roberto ^{[1
]}

机构：

[1] Univ Catania, Dipartimento Sci Chim, Viale A Doria 6, I-95725 Catania, Italy

[2] Univ Messina, Dipartimento Sci Chim Biol Farmaceut & Ambientali, Viale F Stagno dAlcontres 31, I-98166 Messina, Italy

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2020年 / 26卷 / 16期

关键词：

calixarenes; chirality induction; circular dichroism; noncovalent interactions; porphyrinoids; CIRCULAR-DICHROISM; AQUEOUS-SOLUTION; WATER; AMPLIFICATION; SYSTEMS; STOICHIOMETRY; ENCAPSULATION; COORDINATION; RECOGNITION; COMPLEXES;

D O I：

10.1002/chem.202000126

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hierarchical assembly, in aqueous solution, of a new multi-metalloporphyrin/calixarene aggregate has been accomplished. In this supramolecular system transfer of chirality, from the outermost components to the central porphyrin reporter, takes place as a result of favorable and fully noncovalent long-range electronic communication.

引用

页码：3515 / 3518

页数：4

共 15 条

[1] Towards 1D supramolecular chiral assemblies based on porphyrin-calixarene complexes
Gaeta, Massimiliano
Gangemi, Chiara M. A.
Barcellona, Matteo
Travagliante, Gabriele
Milone, Marco
Notti, Anna
Fragala, Maria E.
Pisagatti, Ilenia
Parisi, Melchiorre F.
Purrello, Roberto
D'Urso, Alessandro
NANOSCALE, 2025, 17 (11) : 6530 - 6538
[2] Long-Range Order in Supramolecular π Assemblies in Discrete Multidecker Naphthalenediimides
Keshri, Sudhir Kumar
Ishizuka, Tomoya
Kojima, Takahiko
Matsushita, Yoshitaka
Takeuchi, Masayuki
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 143 (08) : 3238 - 3244
[3] Chiral induction, modulation and locking in porphyrin based supramolecular assemblies with circularly polarized light
Hu, Jingang
Xie, Yifan
Zhang, Hongli
He, Chenlu
Zhang, Qijin
Zou, Gang
CHEMICAL COMMUNICATIONS, 2019, 55 (34) : 4953 - 4956
[4] Enhanced optical asymmetry in supramolecular chiroplasmonic assemblies with long-range order
Lu, Jun
Xue, Yao
Bernardino, Kalil
Zhang, Ning-Ning
Gomes, Weverson R.
Ramesar, Naomi S.
Liu, Shuhan
Hu, Zheng
Sun, Tianmeng
de Moura, Andre Farias
Kotov, Nicholas A.
Liu, Kun
SCIENCE, 2021, 371 (6536) : 1368 - +
[5] Long-Range Plasmon-Assisted Chiral Interactions in Nanocrystal Assemblies
Hu, Li
Liedl, Tim
Martens, Kevin
Wang, Zhiming
Govorov, Alexander O.
ACS PHOTONICS, 2019, 6 (03) : 749 - 756
[6] Induction of chirality in porphyrin-(bis)calixarene assemblies: a mixed covalent-non-covalent vs a fully non-covalent approach
D'Urso, Alessandro
Nicotra, Pietro Francesco
Centonze, Giovanni
Fragala, Maria Elena
Gattuso, Giuseppe
Notti, Anna
Pappalardo, Andrea
Pappalardo, Sebastiano
Parisi, Melchiorre F.
Purrello, Roberto
CHEMICAL COMMUNICATIONS, 2012, 48 (34) : 4046 - 4048
[7] Mechanobiological Induction of Long-Range Contractility and Size Scaling in Cell Assemblies
Dasbiswas, Kinjal
Safran, Samuel
BIOPHYSICAL JOURNAL, 2016, 110 (03) : 624A - 624A
[8] Peptide-Induced Hierarchical Long-Range Order and Photocatalytic Activity of Porphyrin Assemblies
Liu, Kai
Xing, Ruirui
Chen, Chengjun
Shen, Guizhi
Yan, Linyin
Zou, Qianli
Ma, Guanghui
Moehwald, Helmuth
Yan, Xuehai
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (02) : 500 - 505
[9] Extreme Sensitivity of Circular Dichroism to Long-Range Excitonic Couplings in Helical Supramolecular Assemblies
van Dijk, Leon
Bobbert, Peter A.
Spano, Frank C.
JOURNAL OF PHYSICAL CHEMISTRY B, 2010, 114 (02): : 817 - 825
[10] Mechanobiological induction of long-range contractility by diffusing biomolecules and size scaling in cell assemblies
Dasbiswas, K.
Alster, E.
Safran, S. A.
SCIENTIFIC REPORTS, 2016, 6

← 1 2 →