Crystal structure of bis(2-(2-thiazolylazo)-4-methylphenol)cobalt(III)chloride

被引：5

作者：

Mangsup, L

Siripaisarnpipat, S

Chaichit, N

机构：

[1] Kasetsart University,Laboratory of Crystallography and Gemmology, Department of Chemistry, Faculty of Science

[2] Thammasart University,Department of Physics, Faculty of Science and Technology

来源：

ANALYTICAL SCIENCES | 2003年 / 19卷 / 09期

关键词：

D O I：

10.2116/analsci.19.1345

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The reaction between CoCl2.6H(2)O and 2-1-(2-thiazolylazo)-p-cresol (TAC) in acetone resulted in six coordinated cobalt(III) complex, [Co(TAC)(2)]Cl-3. Two TAC ligands coordinate with cobalt ion forming four five membered chelate rings. The cobalt ion is octahedrally coordinated by a phenolic oxygen, azo nitrogen and nitrogen in thiazole rings. Three chloride ions are disordered.

引用

页码：1345 / 1346

页数：2