A Kinetic Study of Oxidative Dehydrogenation of Isobutane to Isobutylene over Chromium Oxide Supported on Lanthanum Carbonate

被引：3
|
作者：
Hoang, M. [1 ]
Mathews, J. F. [2 ]
Pratt, K. C. [3 ]
Xie, Z. [1 ]
机构：
[1] CSIRO Mat Sci & Engn, Clayton, Australia
[2] Monash Univ, Dept Chem Engn, Clayton, Vic 3168, Australia
[3] Swinburne Univ Technol, Hawthorn, Vic 3122, Australia
来源：
KINETICS AND CATALYSIS | 2010年 / 51卷 / 03期
关键词：
SELECTIVE OXIDATION; NICKEL MOLYBDATES; SURFACE-CHEMISTRY; N-BUTANE; CATALYSTS; PROPANE; SILICA; TRANSITION; MECHANISM;
D O I：
10.1134/S0023158410030122
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Kinetics of oxidative dehydrogenation of isobutane to isobutylene over chromium oxide supported on lanthanum carbonate was studied. The formation rate of isobutylene was found to be first order in isobutane and zero order in oxygen concentration and the rate limiting step was the regeneration of active sites by the gas phase oxygen. The formation of CO(2) was due to the consecutive oxidation of isobutylene which occurred on the same active sites used for isobutylene formation, not by the parallel oxidation of isobutane.
引用
收藏
页码：398 / 403
页数：6
相关论文
共 50 条
  • [21] Oxidative dehydrogenation of ethane with carbon dioxide over silica molecular sieves supported chromium oxides: Pore size effect
    Deng, Zhibin
    Ge, Xing
    Zhang, Wenting
    Luo, Shizhong
    Shen, Jun
    Jing, Fangli
    Chu, Wei
    CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2021, 34 : 77 - 86
  • [22] Oxidative dehydrogenation of propane over vanadium catalyst supported on nano-HZSM-5
    Varzaneh, Ali Zeinali
    Moghaddam, Mojtaba Saei
    Darian, Jafar Towfighi
    PETROLEUM CHEMISTRY, 2018, 58 (01) : 13 - 21
  • [23] Preventing Loss of Selectivity during the Oxidative Dehydrogenation of Propane over Supported Vanadium Catalysts
    Al Abdulghani, Abdullah J.
    Kurumbail, Unni
    Dong, Son
    Altvater, Natalie R.
    Dorn, Rick W.
    Cendejas, Melissa C.
    Mcdermott, William P.
    Agbi, Theodore O.
    Queen, Collin M.
    Alvear, Matias
    Head, Ashley R.
    Rossini, Aaron J.
    Hermans, Ive
    ACS CATALYSIS, 2025, 15 (07): : 5557 - 5567
  • [24] Chromium Oxide Supported on Silicalite-1 Zeolite as a Novel Efficient Catalyst for Dehydrogenation of Isobutane Assisted by CO2
    Luo, Yajun
    Miao, Changxi
    Yue, Yinghong
    Yang, Weimin
    Hua, Weiming
    Gao, Zi
    CATALYSTS, 2019, 9 (12)
  • [25] Effects of Reducibility on Propane Oxidative Dehydrogenation over γ-Al2O3-Supported Chromium Oxide-Based Catalysts
    B.Y. Jibril
    S.M. Al-Zahrani
    A.E. Abasaeed
    R. Hughes
    Catalysis Letters, 2003, 87 : 121 - 132
  • [26] Selective Oxidation and Oxidative Dehydrogenation of Isobutane over Hydrothermally Synthesized Mo–V–O Mixed Oxide Catalysts
    Jingqi Guan
    Haiyan Xu
    Ke Song
    Bo Liu
    Fanpeng Shang
    Xiaofang Yu
    Qiubin Kan
    Catalysis Letters, 2008, 126 : 293 - 300
  • [27] Oxidative Dehydrogenation of Propane over Supported Nickel-Molybdenum-Oxide-Based Catalysts
    Putra, Meilana Dharma
    Al-Mesfer, Mohammed Khloofa
    Abasaeed, Ahmed Elhag
    Al-Zahrani, Saeed Mohammed
    JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 2013, 46 (06) : 389 - 395
  • [28] Effects of reducibility on propane oxidative dehydrogenation over γ-Al2O3-supported chromium oxide-based catalysts
    Jibril, BY
    Al-Zahrani, SM
    Abasaeed, AE
    Hughes, R
    CATALYSIS LETTERS, 2003, 87 (3-4) : 121 - 132
  • [29] Combined Oxidative and Non-oxidative Dehydrogenation of n-Butane Over VOX Species Supported on HMS
    Setnicka, M.
    Cicmanec, P.
    Tvaruzkova, E.
    Bulanek, R.
    TOPICS IN CATALYSIS, 2013, 56 (9-10) : 662 - 671
  • [30] Vanadium Oxide Supported on Titanosilicates for the Oxidative Dehydrogenation of n-Butane
    Wang, Cun
    Chen, Jian-Gang
    Xing, Tian
    Liu, Zhao-Tie
    Liu, Zhong-Wen
    Jiang, Jinqiang
    Lu, Jian
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2015, 54 (14) : 3602 - 3610
12345