Electrical and optical properties of Al doped cadmium oxide thin films deposited by radio frequency magnetron sputtering

被引:172
作者
Saha, B. [1 ]
Das, S. [1 ]
Chattopadhyay, K. K. [1 ]
机构
[1] Jadavpur Univ, Dept Phys, Thin Film & Nanosci Lab, Kolkata 700032, India
关键词
cadmium oxide; RF sputtering; AFM; XPS; optical properties; electrical conductivity;
D O I
10.1016/j.solmat.2007.05.025
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Cadmium oxide thin films with different percentages of aluminum doping have been synthesized via radio frequency magnetron sputtering technique. Thin films were deposited on glass and silicon substrates with different percentages of aluminum at a substrate temperature of 573 K and pressure of 0.1 mbar in Ar + O-2 atmosphere. The deposited films were characterized by studying their structural. electrical and optical properties. The X-ray diffraction pattern revealed good crystallinity with preferred (111) orientation in the films. Aluminum doping in CdO thin films were confirmed by X-ray photoelectron spectroscopic studies and actual doping percentages were also measured from it. The optical band gap was found to decrease first and then increase with increasing percentages of aluminum concentrations. The electrical conductivity was found to increase with increase of aluminum doping concentration up to 5% but for higher doping concentration (> 5%) the conductivity was found to decrease. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:1692 / 1697
页数:6
相关论文
共 33 条
[1]   Size-dependent optical properties of sputter-deposited nanocrystalline p-type transparent CuAlO2 thin films -: art. no. 084308 [J].
Banerjee, AN ;
Chattopadhyay, KK .
JOURNAL OF APPLIED PHYSICS, 2005, 97 (08)
[2]  
Chopra K.L., 1983, THIN FILM SOLAR CELL, P346
[3]   TRANSPARENT CONDUCTORS - A STATUS REVIEW [J].
CHOPRA, KL ;
MAJOR, S ;
PANDYA, DK .
THIN SOLID FILMS, 1983, 102 (01) :1-46
[4]  
CHOPRA KL, 1969, THIN FILM PHENOMENA, P23
[5]   DEGENERATE CADMIUM-OXIDE FILMS FOR ELECTRONIC DEVICES [J].
CHU, TL ;
CHU, SS .
JOURNAL OF ELECTRONIC MATERIALS, 1990, 19 (09) :1003-1005
[6]   Some physical properties of Sn-doped CdO thin films prepared by chemical bath deposition [J].
de Leon-Gutierrez, L. R. ;
Cayente-Romero, J. J. ;
Peza-Tapia, J. M. ;
Barrera-Calva, E. ;
Martinez-Flores, J. C. ;
Ortega-Lopez, M. .
MATERIALS LETTERS, 2006, 60 (29-30) :3866-3870
[7]   Band-gap shrinkage in n-type-doped CdO probed by photoemission spectroscopy [J].
Dou, Y ;
Fishlock, T ;
Egdell, RG ;
Law, DSL ;
Beamson, G .
PHYSICAL REVIEW B, 1997, 55 (20) :13381-13384
[8]   Chemical and thin-film strategies for new transparent conducting oxides [J].
Freeman, AJ ;
Poeppelmeier, KR ;
Mason, TO ;
Chang, RPH ;
Marks, TJ .
MRS BULLETIN, 2000, 25 (08) :45-51
[9]   Preparation of CuAlO2 nanocrystalline transparent thin films with high conductivity [J].
Gao, SM ;
Zhao, Y ;
Gou, PP ;
Chen, N ;
Xie, Y .
NANOTECHNOLOGY, 2003, 14 (05) :538-541
[10]   Effect of fluorine doping on semiconductor to metal-like transition and optical properties of cadmium oxide thin films deposited by sol-gel process [J].
Ghosh, P ;
Das, S ;
Kundoo, S ;
Chattopadhyay, K .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2005, 34 (02) :173-179