Fervent Hype behind Magnesium Batteries: An Open Call to Synthetic Chemists-Electrolytes and Cathodes Needed

被引:218
作者
Muldoon, John [1 ]
Bucur, Claudiu B. [1 ]
Gregory, Thomas [2 ]
机构
[1] Toyota Res Inst North Amer, 1555 Woodridge Ave, Ann Arbor, MI 48105 USA
[2] Borealis Technol Solut LLC, Midland, MI 48642 USA
关键词
conversion cathodes; electrolyte; insertion cathode; magnesium battery; organic cathodes; MG-ION BATTERIES; WIDE ELECTROCHEMICAL WINDOWS; ALUMINUM-CHLORIDE COMPLEX; CHEVREL-PHASE CATHODE; HIGH-ENERGY-DENSITY; CHEMICAL INTERCALATION; RECHARGEABLE BATTERIES; SECONDARY BATTERIES; STRUCTURAL-ANALYSIS; MOLECULAR-DYNAMICS;
D O I
10.1002/anie.201700673
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Magnesium metal is a superior anode which has double the volumetric capacity of lithium metal and has a negative reduction potential of -2.37V vs. the standard hydrogen electrode. A major benefit of magnesium is the apparent lack of dendrite formation during charging which is one of the crucial concerns of using a lithium metal anode. In this Review, we highlight the foremost research in the development of electrolytes and cathodes and discuss some of the significant challenges which must be overcome in realizing a practical magnesium battery.
引用
收藏
页码:12064 / 12084
页数:21
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