Hydrogen Production by Methane Dry Reforming on Supported Nickel Catalysts - Enhanced Stability of the Reforming Process

被引：0

作者：

Nakajima, Akiyuki ^{[1
]}

Taniya, Keita ^{[1
]}

Kitano, Yuki ^{[1
]}

Ichihashi, Yuichi ^{[1
]}

Nishiyama, Satoru ^{[1
]}

机构：

[1] Kobe Univ, Dept Chem Sci & Engn, Grad Sch Engn, Nada Ku, Kobe, Hyogo 6578501, Japan

来源：

PROCESS AND ADVANCED MATERIALS ENGINEERING | 2014年 / 625卷

关键词：

Dry reforming; Methane; Carbon dioxide; Hydrogen formation; Deactivation; Carbon deposition; Cerium addition;

D O I：

10.4028/www.scientific.net/AMM.625.320

中图分类号：

TH [机械、仪表工业];

学科分类号：

0802 ;

摘要：

Dry reforming reaction of CH4 by CO2 was carried out over alumina-supported Ni catalysts. Main products were H-2 and CO with small amount of H2O by-production because of reverse water gas shift reaction. The activity was gradually decreased with time on stream by carbon deposition. The addition of Ce component was investigated to improve the catalyst stability. The Ce addition brought decrease of carbon deposition during the reaction. The role of Ce has been considered that an inactive coke formation is significantly suppressed.

引用

页码：320 / 323

页数：4