Nanocellulose-Based Materials for Water Treatment: Adsorption, Photocatalytic Degradation, Disinfection, Antifouling, and Nanofiltration

被引:78
作者
Salama, Ahmed [1 ]
Abouzeid, Ragab [1 ,2 ]
Leong, Wei Sun [3 ]
Jeevanandam, Jaison [4 ]
Samyn, Pieter [5 ]
Dufresne, Alain [2 ]
Bechelany, Mikhael [6 ]
Barhoum, Ahmed [7 ,8 ]
机构
[1] Natl Res Ctr, Cellulose & Paper Dept, 33 El Bohouth St, Giza 12622, Egypt
[2] Univ Grenoble Alpes, CNRS, Grenoble INP, F-38000 Grenoble, France
[3] Natl Univ Singapore, Dept Mat Sci & Engn, Singapore 117575, Singapore
[4] Univ Madeira, CQM Ctr Quim Madeira, MMRG, P-9020105 Funchal, Portugal
[5] Univ Hasselt, Inst Mat Res MOI MOMEC Appl & Analyt Chem, B-3590 Diepenbeek, Belgium
[6] Univ Montpellier, CNRS, ENSCM, Inst Europeen Membranes,IEM,UMR 5635, F-34090 Montpellier, France
[7] Helwan Univ, Fac Sci, Chem Dept, NanoStruc Res Grp, Cairo 11795, Helwan, Egypt
[8] Dublin City Univ, Sch Chem Sci, Dublin D09 Y074 9, Ireland
关键词
nanoparticles; nanocrystals; nanowhiskers; nanofibers; hydrogels; bacterial cellulose; surface functionalization; membranes filtration; HEAVY-METAL IONS; ZINC-OXIDE NANOPARTICLES; WASTE PULP RESIDUES; IN-SITU SYNTHESIS; CELLULOSE NANOCRYSTALS; BACTERIAL CELLULOSE; EFFECTIVE REMOVAL; AQUEOUS-SOLUTION; METHYLENE-BLUE; CARBOXYMETHYL CELLULOSE;
D O I
10.3390/nano11113008
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nanocelluloses are promising bio-nano-materials for use as water treatment materials in environmental protection and remediation. Over the past decades, they have been integrated via novel nanoengineering approaches for water treatment processes. This review aims at giving an overview of nanocellulose requirements concerning emerging nanotechnologies of waster treatments and purification, i.e., adsorption, absorption, flocculation, photocatalytic degradation, disinfection, antifouling, ultrafiltration, nanofiltration, and reverse osmosis. Firstly, the nanocellulose synthesis methods (mechanical, physical, chemical, and biological), unique properties (sizes, geometries, and surface chemistry) were presented and their use for capturing and removal of wastewater pollutants was explained. Secondly, different chemical modification approaches surface functionalization (with functional groups, polymers, and nanoparticles) for enhancing the surface chemistry of the nanocellulose for enabling the effective removal of specific pollutants (suspended particles, microorganisms, hazardous metals ions, organic dyes, drugs, pesticides fertilizers, and oils) were highlighted. Thirdly, new fabrication approaches (solution casting, thermal treatment, electrospinning, 3D printing) that integrated nanocelluloses (spherical nanoparticles, nanowhiskers, nanofibers) to produce water treatment materials (individual composite nanoparticles, hydrogels, aerogels, sponges, membranes, and nanopapers) were covered. Finally, the major challenges and future perspectives concerning the applications of nanocellulose based materials in water treatment and purification were highlighted.
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页数:43
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