"Clicking" Polymers or Just Efficient Linking: What Is the Difference?

被引：535

作者：

Barner-Kowollik, Christopher ^{[1
]}

Du Prez, Filip E. ^{[2
]}

Espeel, Pieter ^{[2
]}

Hawker, Craig J. ^{[3
]}

Junkers, Tanja ^{[4
]}

Schlaad, Helmut ^{[5
]}

Van Camp, Wim ^{[2
]}

机构：

[1] KIT, ITCP, Engesserstr 18, D-76128 Karlsruhe, Germany

[2] Univ Ghent, Polymer Chem Res Grp, Ghent, Belgium

[3] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA

[4] Hasselt Univ, Inst Mat Res, IMO, Diepenbeek, Belgium

[5] Max Planck Inst Colloids & Interfaces, D-14424 Potsdam, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 01期

关键词：

click reactions; polymer chemistry; polymer conjugation; selectivity; CHEMISTRY;

D O I：

10.1002/anie.201003707

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The "click" trick: Many reactions are classified as click reactions even though some are limited to certain applications. Thus, there is danger that the term "click" will become meaningless over time and simply a synonym for "successful". To prevent this, the original click criteria are evaluated in this Essay specifically for the synthetic polymer field and a set of criteria are specified that distinguishes click from other efficient reactions. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：60 / 62

页数：3

共 18 条

[1] Has Click Chemistry Lead to a Paradigm Shift in Polymer Material Design? [J].

Barner-Kowollik, Christopher ;

Inglis, Andrew J. .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 2009, 210 (12) :987-992

[2]

Becer C.R., 2009, Angew. Chem, V121, P4998

[3] Click Chemistry beyond Metal-Catalyzed Cycloaddition [J].

Becer, C. Remzi ;

Hoogenboom, Richard ;

Schubert, Ulrich S. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (27) :4900-4908

[4] 'Click' chemistry in polymer and material science: An update [J].

Binder, Wolfgang H. ;

Sachsenhofer, Robert .

MACROMOLECULAR RAPID COMMUNICATIONS, 2008, 29 (12-13) :952-981

[5] Clicking polymers: a straightforward approach to novel macromolecular architectures [J].

Fournier, David ;

Hoogenboom, Richard ;

Schubert, Ulrich S. .

CHEMICAL SOCIETY REVIEWS, 2007, 36 (08) :1369-1380

[6] Marrying click chemistry with polymerization: expanding the scope of polymeric materials [J].

Golas, Patricia L. ;

Matyjaszewski, Krzysztof .

CHEMICAL SOCIETY REVIEWS, 2010, 39 (04) :1338-1354

[7] Polypseudopeptides with Variable Stereochemistry: Synthesis via Click-Chemistry, Postfunctionalization, and Conformational Behavior in Solution [J].

Hartwig, Sebastian ;

Hecht, Stefan .

MACROMOLECULES, 2010, 43 (01) :242-248

[8] The convergence of synthetic organic and polymer chemistries [J].

Hawker, CJ ;

Wooley, KL .

SCIENCE, 2005, 309 (5738) :1200-1205

[9] Bringing efficiency to materials synthesis: The philosophy of click chemistry [J].

Hawker, Craig J. ;

Fokin, Valery V. ;

Finn, M. G. ;

Sharpless, K. Barry .

AUSTRALIAN JOURNAL OF CHEMISTRY, 2007, 60 (06) :381-383

[10] Applications of Orthogonal "Click" Chemistries in the Synthesis of Functional Soft Materials [J].

Iha, Rhiannon K. ;

Wooley, Karen L. ;

Nystrom, Andreas M. ;

Burke, Daniel J. ;

Kade, Matthew J. ;

Hawker, Craig J. .

CHEMICAL REVIEWS, 2009, 109 (11) :5620-5686

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