Synthesis and Characterization of NH4V(Gly)3(PO4)2•H2O

被引:0
作者
Wei, Bo [1 ]
Cao, Huiqun [1 ]
Sun, Jianmin [2 ]
Lv, Yujuan [1 ]
机构
[1] Shenzhen Univ, Coll Chem & Chem Engn, Shenzhen 518060, Peoples R China
[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China
来源
2009 3RD INTERNATIONAL CONFERENCE ON BIOINFORMATICS AND BIOMEDICAL ENGINEERING, VOLS 1-11 | 2009年
关键词
vanadium; glycine; hydrothermal synthesis; ligand; complex; VANADIUM(III) COMPLEXES; ACID;
D O I
暂无
中图分类号
R318 [生物医学工程];
学科分类号
0831 ;
摘要
A new vanadium-glycine complex (NH4V(Gly)(3)(PO4)(2 center dot)H2O) was synthesized in hydrothermal condition and characterized by XRD, FTIR, SEM and TG-DSC techniques. The results indicate that glycine and water exist in the crystal framework as ligand coordinating with vanadium. The SEM images show that the single crystals are homogeneous in crystal size and shape, and show a good crystalline performance. The size of crystals is about 20x20x20 mu m(3). It has a certain potential of application in studying the relationships between the chemical and biological properties of vanadium compounds.
引用
收藏
页码:1000 / +
页数:2
相关论文
共 20 条
[1]   Vanadium(III) binding strengths of small biomolecules [J].
Buglyó, P ;
Nagy, EM ;
Sóvágó, I .
PURE AND APPLIED CHEMISTRY, 2005, 77 (09) :1583-1594
[2]   Aqueous chemistry of the vanadiumIII (VIII) and the VIII-dipicolinate systems and a comparison of the effect of three oxidation states of vanadium compounds on diabetic hyperglycemia in rats [J].
Buglyó, P ;
Crans, DC ;
Nagy, EM ;
Lindo, RL ;
Yang, LQ ;
Smee, JJ ;
Jin, WZ ;
Chi, LH ;
Godzala, ME ;
Willsky, GR .
INORGANIC CHEMISTRY, 2005, 44 (15) :5416-5427
[3]   New insights into the metal ion-peptide hydroxamate interactions:: Metal complexes of primary hydroxamic acid, derivatives of common dipeptides in aqueous solution [J].
Buglyo, Peter ;
Nagy, Eszter Marta ;
Farkas, Etelka ;
Sovago, Imre ;
Sanna, Daniele ;
Micera, Giovanni .
POLYHEDRON, 2007, 26 (08) :1625-1633
[4]   Vanadium(III) complexes with L-histidine in aqueous solution [J].
Bukietynska, K ;
Karwecka, Z ;
Podsiadly, H .
POLYHEDRON, 1997, 16 (15) :2613-2620
[5]   Complexes of vanadium(III) with L-alanine and L-aspartic acid [J].
Bukietynska, K ;
Podsiadly, H ;
Karwecka, Z .
JOURNAL OF INORGANIC BIOCHEMISTRY, 2003, 94 (04) :317-325
[6]   Fluoride-assisted stabilisation of amino acid complexes of vanadium - Synthesis and characterisation [J].
Chaudhuri, MK ;
Chettri, SK ;
Paul, PC ;
Srinivas, P .
JOURNAL OF FLUORINE CHEMISTRY, 1996, 78 (02) :131-135
[7]   Comparison of the therapeutic effects of two vanadium complexes administered at low doses on benzo[a]pyrene-induced malignant tumors in rats [J].
Evangelou, A ;
Karkabounas, S ;
Kalpouzos, G ;
Malamas, M ;
Liasko, R ;
Stefanou, D ;
Vlahos, AT ;
Kabanos, TA .
CANCER LETTERS, 1997, 119 (02) :221-225
[8]   Synthesis and X-ray structural characterization of tris(L-glycinato) vanadium(III) and trans-tetraquadichlorovanadium(III) chloride [J].
Fry, Fiona H. ;
Dougan, Brenda ;
McCann, Nichola ;
Willis, Anthony C. ;
Ziegler, Christopher J. ;
Brasch, Nicola E. .
INORGANICA CHIMICA ACTA, 2008, 361 (08) :2321-2326
[9]   Synthesis and characterization of new oxodiperoxovanadate complexes containing coordinated amino acids [J].
Gerbase, AE ;
Martinelli, M ;
Fagundes, LG ;
Stefani, V ;
Da Silva, SJ .
JOURNAL OF COORDINATION CHEMISTRY, 1999, 47 (03) :451-458
[10]   Stabilizing factors for vanadium(IV) in amavadin [J].
Hubregtse, Ton ;
Hanefeld, Ulf ;
Arends, Isabel W. C. E. .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2007, 2007 (15) :2413-2422