Steam-Stable Zeolitic Imidazolate Framework ZIF-90 Membrane with Hydrogen Selectivity through Covalent Functionalization

被引：492
作者：
Huang, Aisheng [1 ]
Dou, Wei [2 ]
Caro, Juergen [1 ]
机构：
[1] Leibniz Univ Hannover, Inst Phys Chem & Elektrochem, D-30167 Hannover, Germany
[2] Lanzhou Univ, Dept Chem, Lanzhou 730000, Peoples R China
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 44期
关键词：
METAL-ORGANIC FRAMEWORK; MOLECULAR-SIEVE MEMBRANE; 3-AMINOPROPYLTRIETHOXYSILANE; SEPARATION; GROWTH; DESIGN;
D O I：
10.1021/ja108774v
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel covalent functionalization strategy was developed to prepare reproducible ZIF-90 molecular sieve membranes by using 3-aminopropyltriethoxysilane as a covalent linker between the ZIF-90 layer and Al2O3 support via imines condensation. The ZIF-90 membranes show high thermal and hydrothermal stabilities, and they allow the separation of hydrogen from larger gases by molecular sieving.
引用
收藏
页码：15562 / 15564
页数：3
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