D-A Copolymers Based on a Pentacyclic Acceptor Unit and a 3,3′-Difluoro2,2′-bithiophene for Solar Cells

被引：4

作者：

Cao, Jia-min ^{[1
]}

Qian, Liu ^{[1
]}

He, Dan ^{[1
]}

Xiao, Zuo ^{[1
]}

Ding, Li-ming ^{[1
]}

机构：

[1] Chinese Acad Sci, Natl Ctr Nanosci & Technol, Key Lab Nanosyst & Hierarch Fabricat, Ctr Excellence Nanosci, Beijing 100190, Peoples R China

来源：

CHINESE JOURNAL OF POLYMER SCIENCE | 2017年 / 35卷 / 12期

基金：

中国国家自然科学基金;

关键词：

D-A copolymers; Fluorination; Open-circuit voltage; Polymer solar cells; PHOTOVOLTAIC APPLICATIONS; BUILDING-BLOCK; POLYMER; PERFORMANCE; AGGREGATION; EFFICIENCY;

D O I：

10.1007/s10118-017-1996-4

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A D-A copolymer, P2FBTTPTI, was developed by copolymerizing a pentacyclic acceptor unit, thieno[2',3':5,6]pyrido[3,4-g]thieno[3,2-c]isoquinoline-5,11(4H,10H)-dione (TPTI), with 3,3'-difluoro-2,2'-bithiophene (2FBT). P2FBTTPTI possessed a low highest occupied molecular orbital (HOMO) energy level (-5.50 eV) and a good hole mobility (4.14 x 10(-4) cm(2).V-1.s(-1)). P2FBTTPTI:PC71BM solar cells gave a decent power conversion efficiency (PCE) of 7.64% and a high open-circuit voltage (V-oc) of 0.95 V.

引用

页码：1457 / 1462

页数：6

共 25 条

[1] A heptacyclic acceptor unit developed for D-A copolymers used in polymer solar cells [J].

Cao, Jiamin ;

Qian, Liu ;

Ding, Liming .

POLYMER CHEMISTRY, 2016, 7 (05) :1027-1030

[2] Hexacyclic lactam building blocks for highly efficient polymer solar cells [J].

Cao, Jiamin ;

Zuo, Chuantian ;

Du, Bin ;

Qiu, Xiaohui ;

Ding, Liming .

CHEMICAL COMMUNICATIONS, 2015, 51 (60) :12122-12125

[3]

Cao JM, 2015, CHEM COMMUN, V51, P11830, DOI 10.1039/c5cc03620h

[4] A pentacyclic aromatic lactam building block for efficient polymer solar cells [J].

Cao, Jiamin ;

Liao, Qiaogan ;

Du, Xiaoyan ;

Chen, Jianhua ;

Xiao, Zuo ;

Zuo, Qiqun ;

Ding, Liming .

ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (11) :3224-3228

[5] Examining the Effect of the Dipole Moment on Charge Separation in Donor-Acceptor Polymers for Organic Photovoltaic Applications [J].

Carsten, Bridget ;

Szarko, Jodi M. ;

Son, Hae Jung ;

Wang, Wei ;

Lu, Luyao ;

He, Feng ;

Rolczynski, Brian S. ;

Lou, Sylvia J. ;

Chen, Lin X. ;

Yu, Luping .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (50) :20468-20475

[6] Polymer solar cells with enhanced open-circuit voltage and efficiency [J].

Chen, Hsiang-Yu ;

Hou, Jianhui ;

Zhang, Shaoqing ;

Liang, Yongye ;

Yang, Guanwen ;

Yang, Yang ;

Yu, Luping ;

Wu, Yue ;

Li, Gang .

NATURE PHOTONICS, 2009, 3 (11) :649-653

[7] Overcoming Interfacial Losses in Solution-Processed Organic Multi-Junction Solar Cells [J].

Du, Xiaoyan ;

Lytken, Ole ;

Killian, Manuela S. ;

Cao, Jiamin ;

Stubhan, Tobias ;

Turbiez, Mathieu ;

Schmuki, Patrik ;

Steinrueck, Hans-Peter ;

Ding, Liming ;

Fink, Rainer H. ;

Li, Ning ;

Brabec, Christoph J. .

ADVANCED ENERGY MATERIALS, 2017, 7 (05)

[8] A New Polythiophene Derivative for High Efficiency Polymer Solar Cells with PCE over 9% [J].

Fan, Qunping ;

Su, Wenyan ;

Guo, Xia ;

Guo, Bing ;

Li, Wanbin ;

Zhang, Youdi ;

Wang, Kun ;

Zhang, Maojie ;

Li, Yongfang .

ADVANCED ENERGY MATERIALS, 2016, 6 (14)

[9] Imide- and Amide-Functionalized Polymer Semiconductors [J].

Guo, Xugang ;

Facchetti, Antonio ;

Marks, Tobin J. .

CHEMICAL REVIEWS, 2014, 114 (18) :8943-9021

[10] Furan-containing conjugated polymers for organic solar cells [J].

Islam, Amjad ;

Liu, Zhi-yang ;

Peng, Rui-xiang ;

Jiang, Wei-gang ;

Lei, Tao ;

Li, Wang ;

Zhang, Lei ;

Yang, Rong-juan ;

Guan, Qian ;

Ge, Zi-yi .

CHINESE JOURNAL OF POLYMER SCIENCE, 2017, 35 (02) :171-183

← 1 2 3 →