Series of resorcin[4]arene-based lanthanide coordination polymers and selective luminescent sensing properties

被引：4
作者：
Ma, Li [1 ]
Dong, Hui [1 ]
Liu, Ying-Ying [1 ]
Xu, Guo-Hai [2 ]
Ma, Jian-Fang [1 ]
机构：
[1] Northeast Normal Univ, Dept Chem, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China
[2] Garman Normal Univ, Sch Chem & Chem Engn, Key Lab Jiangxi Univ Funct Mat Chem, Ganzhou 341000, Jiangxi, Peoples R China
来源：
JOURNAL OF LUMINESCENCE | 2019年 / 205卷
基金：
中国国家自然科学基金;
关键词：
Coordination polymers; Resorcin[4]arene; Lanthanide; Crystal structure; Luminescent detection; METAL-ORGANIC FRAMEWORKS; ION EXCHANGE; FAMILY; SENSOR; MOFS; COMPLEXES; VAPORS; AMINE;
D O I：
10.1016/j.jlumin.2018.09.021
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
By using tetracarboxylatoresorcin [4]arene 2,8,14,20-tetrapentyl-6,12,18,23-tetra- methoxy-4,10,16,22-tetracarboxymethoxy-resorcinMarene (H4L), eight lanthanide-based coordination polymers (CPs), [M(HL)(DMF) (H2O)(2)]center dot 3H(2)O (M = Tb 1, Eu 2, Gd 3, Yb 4 and Sm 5) and [M(HL)(DMF)(H2O)] (M = Ce 6, Pr 7 and La 8), have been constructed. Isostructural CPs 1-5 exhibit charming ribbons built with rare earth cations and cup-like HL3- anions. The ribbons are lengthened by hydrogen bonds to constitute supramolecular layers, respectively. CPs 6-8 are isostructural and show unique layer networks. The luminescent properties of 1 and 2 in solid states were studied. The detection of CPs 1 and 2 towards metal cations, polyoxometalates (POMs) and organic small molecules by luminescent quenching and enhancement process has been systematically investigated.
引用
收藏
页码：228 / 236
页数：9
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