Ag2S quantum dot-sensitized solar cells

被引:208
作者
Tubtimtae, Auttasit [1 ,2 ]
Wu, Kun-Lun [1 ,2 ]
Tung, Hao-Yu [1 ,2 ]
Lee, Ming-Way [1 ,2 ]
Wang, Gou Jen [3 ,4 ]
机构
[1] Natl Chung Hsing Univ, Dept Phys, Taichung 402, Taiwan
[2] Natl Chung Hsing Univ, Inst Nanosci, Taichung 402, Taiwan
[3] Natl Chung Hsing Univ, Dept Mech Engn, Taichung 402, Taiwan
[4] Natl Chung Hsing Univ, Inst Biomed Engn, Taichung 402, Taiwan
关键词
Quantum dots; Solar cells; Silver sulfide; Successive ionic layer adsorption; Reaction deposition; TIO2; SULFIDE; ENERGY; CDS;
D O I
10.1016/j.elecom.2010.06.006
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
We present a new photosensitizer - Ag2S quantum dots (QDs) - for solar cells. The QDs were grown by the successive ionic layer adsorption and reaction deposition method. The assembled Ag2S-QD solar cells yield a best power conversion efficiency of 1.70% and a short-circuit current of 1.54 mA/cm(2) under 10.8% sun. The solar cells have a maximal external quantum efficiency (EQE) or 50% at lambda=530 nm and an average EQE of similar to 42% over the spectral range of 400-1000 nm. The effective photovoltaic range covers the visible and near-infrared spectral regions and is similar to 2-4 times broader than that of the cadmium chalcogenide systems - CdS and CdSe. The results show that Ag2S QDs can be used as a highly efficient and broadband sensitizer for solar cells. (C) 2010 Elsevier By. All rights reserved.
引用
收藏
页码:1158 / 1160
页数:3
相关论文
共 18 条
  • [1] Influence of the local absorber layer thickness on the performance of ZnO nanorod solar cells
    Belaidi, Abdelhak
    Dittrich, Thomas
    Kieven, David
    Tornow, Julian
    Schwarzburg, Klaus
    Lux-Steiner, Martha
    [J]. PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS, 2008, 2 (04): : 172 - 174
  • [2] Highly efficient CdSe quantum-dot-sensitized TiO2 photoelectrodes for solar cell applications
    Fan, Sheng-Qiang
    Kim, Duckhyun
    Kim, Jeum-Jong
    Jung, Dong Woon
    Kang, Sang Ook
    Ko, Jaejung
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2009, 11 (06) : 1337 - 1339
  • [3] QUANTUM-SIZE EFFECTS IN THE STUDY OF CHEMICAL SOLUTION DEPOSITION MECHANISMS OF SEMICONDUCTOR-FILMS
    GORER, S
    HODES, G
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (20) : 5338 - 5346
  • [4] Sb2S3-Sensitized Nanoporous TiO2 Solar Cells
    Itzhaik, Yafit
    Niitsoo, Olivia
    Page, Miles
    Hodes, Gary
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (11) : 4254 - 4256
  • [5] KITOVA S, 1994, J IMAGING SCI TECHN, V38, P484
  • [6] CdSe quantum dot-sensitized solar cells exceeding efficiency 1% at full-sun intensity
    Lee, Hyo Joong
    Yum, Jun-Ho
    Leventis, Henry C.
    Zakeeruddin, Shaik M.
    Haque, Saif A.
    Chen, Peter
    Seok, Sang Il
    Graetzel, Michael
    Nazeeruddin, Md. K.
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (30) : 11600 - 11608
  • [7] Highly Efficient Quantum-Dot-Sensitized Solar Cell Based on Co-Sensitization of CdS/CdSe
    Lee, Yuh-Lang
    Lo, Yi-Siou
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (04) : 604 - 609
  • [8] Limiting efficiencies for photovoltaic energy conversion in multigap systems
    Marti, A
    Araujo, GL
    [J]. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1996, 43 (02) : 203 - 222
  • [9] Composition and size-dependent extinction coefficient of colloidal PbSe quantum dots
    Moreels, Iwan
    Lambert, Karel
    De Muynck, David
    Vanhaecke, Frank
    Poelman, Dirk
    Martins, Jose C.
    Allan, Guy
    Hens, Zeger
    [J]. CHEMISTRY OF MATERIALS, 2007, 19 (25) : 6101 - 6106
  • [10] Combined experimental and DFT-TDDFT computational study of photoelectrochemical cell ruthenium sensitizers
    Nazeeruddin, MK
    De Angelis, F
    Fantacci, S
    Selloni, A
    Viscardi, G
    Liska, P
    Ito, S
    Bessho, T
    Grätzel, M
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (48) : 16835 - 16847