Agro-Waste Extract Based Solvents: Emergence of Novel Green Solvent for the Design of Sustainable Processes in Catalysis and Organic Chemistry

被引：69

作者：

Sarmah, Manashi ^{[1
]}

Mondal, Manoj ^{[1
]}

Bora, Utpal ^{[1
]}

机构：

[1] Tezpur Univ, Dept Chem Sci, Tezpur 784028, Assam, India

来源：

CHEMISTRYSELECT | 2017年 / 2卷 / 18期

关键词：

Bio-based solvent; Green chemistry; Metal catalysis; CROSS-COUPLING REACTIONS; BAEYER-VILLIGER OXIDATION; ARYLBORONIC ACIDS; MOLECULAR-OXYGEN; ROOM-TEMPERATURE; METAL-CATALYSTS; HENRY REACTION; SUPERCRITICAL FLUIDS; EFFICIENT CATALYST; BIPHASIC SYSTEM;

D O I：

10.1002/slct.201700580

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Water extract of agro-waste ash (AWEs) has emerged as an efficient non-conventional solvent for practicing green reactions in catalysis and organic chemistry. The recent advancements made in the field of agro-waste-derived reaction media have witnessed a major advancement in reactions like SuzukiMiyaura, Sonogashira, Dakin, Henry, peptide synthesis and ipsohydroxylation. Traditionally, these reactions were conducted in conventional volatile organic solvents (VOCs) derived from non-renewable petroleum sources. During the course of these reactions AWEs displays distinct properties, such as, in situ base, homogeneous catalyst, nano reactor and reducing agent. This review summarizes the recent developments made in the application of AWEs in important reactions emphasizing on the key utilities and limitations in order to facilitate the further progress of this exciting area of research.

引用

页码：5180 / 5188

页数：9

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