Fabrication and performance evaluation of new nanocomposite membranes based on sulfonated poly(phthalazinone ether ketone) for PEM fuel cells

被引：20

作者：

Hooshyari, Khadijeh ^{[1
]}

Heydari, Samira ^{[2
,3
]}

Javanbakht, Mehran ^{[2
,3
]}

Beydaghi, Hossein ^{[4
]}

Enhessari, Morteza ^{[5
]}

机构：

[1] Urmia Univ, Fac Chem, Dept Appl Chem, Orumiyeh, Iran

[2] Amirkabir Univ Technol, Dept Chem, Tehran, Iran

[3] Amirkabir Univ Technol, Renewable Energy Res Ctr, Solar Cell & Fuel Cell Lab, Tehran, Iran

[4] Ist Italiano Tecnol, Graphene Labs, I-16163 Genoa, Italy

[5] Islamic Azad Univ, Dept Chem, Naragh Branch, Naragh, Iran

来源：

RSC ADVANCES | 2020年 / 10卷 / 05期

关键词：

POLYMER ELECTROLYTE MEMBRANE; COMPOSITE MEMBRANES; PROTON CONDUCTIVITY; FE2TIO5; NANOPARTICLES; POLYBENZIMIDAZOLE; NAFION; SPEEK; IMPROVEMENT; WATER;

D O I：

10.1039/c9ra08893h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The purpose of this work is to enhance the proton conductivity and fuel cell performance of sulfonated poly(phthalazinone ether ketone) (SPPEK) as a proton exchange membrane through the application of SrTiO3 perovskite nanoparticles. Nanocomposite membranes based on SPPEK and SrTiO3 perovskite nanoparticles were prepared via a casting method. The highest proton conductivity of nanocomposite membranes obtained was 120 mS cm(-1) at 90 degrees C and 95% RH. These enhancements could be related to the hygroscopic structure of SrTiO3 perovskite nanoparticles and the formation of hydrogen bonds between nanoparticles and water molecules. The satisfactory power density, 0.41 W cm(-2) at 0.5 V and 85 degrees C, of the nanocomposite membrane (5 wt% content of nanoparticles) confirms their potential for application in the PEM fuel cells.

引用

页码：2709 / 2721

页数：13

共 57 条

[21] Novel composite membranes based on PBI and dicationic ionic liquids for high temperature polymer electrolyte membrane fuel cells [J].