Recent developments in transition metal diaryl chemistry

被引：68
|
作者：
Kays, Deborah L. [1 ]
机构：
[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England
来源：
DALTON TRANSACTIONS | 2011年 / 40卷 / 04期
基金：
英国工程与自然科学研究理事会;
关键词：
BULKY TERPHENYL LIGANDS; DOPED ZNSE NANOCRYSTALS; JAHN-TELLER DISTORTION; MAIN-GROUP ELEMENTS; HIGH-SPIN IRON(II); CRYSTAL-STRUCTURES; TRIMETHYLSILYLMETHYL COMPOUNDS; ORGANOMETALLIC COMPOUNDS; 2-COORDINATE IRON(II); REDUCTIVE ELIMINATION;
D O I：
10.1039/c0dt01247e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
This Perspective discusses the synthesis and reactivity of low-coordinate transition metal diaryl complexes. The development of sterically demanding ligands, in particular m-terphenyls is facilitating the isolation of complexes featuring two-coordinate open-shell transition metal centres. These coordinatively unsaturated complexes are now being investigated for their reaction chemistry, which is not only contributing to the elucidation of the structure and bonding within these systems but is also leading to the formation of novel compounds.
引用
收藏
页码：769 / 778
页数：10
相关论文
共 50 条
  • [21] Recent developments of transition metal phosphides as catalysts in the energy conversionfield
    Pei, Yu
    Cheng, Yu
    Chen, Jiyi
    Smith, Will
    Dong, Pei
    Ajayan, Pulickel M.
    Ye, Mingxin
    Shen, Jianfeng
    JOURNAL OF MATERIALS CHEMISTRY A, 2018, 6 (46) : 23220 - 23243
  • [22] Recent developments in transition metal ion detection by luminescent chemosensors
    Bargossi, C
    Fiorini, MC
    Montalti, M
    Prodi, L
    Zaccheroni, N
    COORDINATION CHEMISTRY REVIEWS, 2000, 208 : 17 - 32
  • [23] Nitrogen Fixation Catalyzed by Transition Metal Complexes: Recent Developments
    Stucke, Nadja
    Floeser, Benedikt M.
    Weyrich, Thomas
    Tuczek, Felix
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2018, (12) : 1337 - 1355
  • [24] Special issue: Recent developments in metal alkynyl organometallic chemistry - Preface
    Humphrey, MG
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 670 (1-2) : 1 - 1
  • [25] Recent developments in fluoropolymer chemistry
    Feiring, A.E.
    Proceedings of the IUPAC International Symposium on Macromolecules, 1988,
  • [26] Recent Developments in Azaborinine Chemistry
    Belanger-Chabot, Guillaume
    Braunschweig, Holger
    Roy, Dipak Kumar
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2017, (38-39) : 4353 - 4368
  • [27] Recent developments of cyclopropene chemistry
    Zhu, Zhi-Bin
    Wei, Yin
    Shi, Min
    CHEMICAL SOCIETY REVIEWS, 2011, 40 (11) : 5534 - 5563
  • [28] RECENT DEVELOPMENTS IN PHOTOELECTROANALYTICAL CHEMISTRY
    BERRY, WF
    ELBICKI, JM
    WEBER, SG
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1986, 191 : 27 - ANYL
  • [29] RECENT DEVELOPMENTS IN PHOSPHASILENE CHEMISTRY
    VANDENWINKEL, Y
    BASTIAANS, HMM
    BICKELHAUPT, F
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1990, 49 (1-4): : 333 - 336
  • [30] RECENT DEVELOPMENTS IN ORGANOMETALLIC CHEMISTRY
    GREEN, MLH
    PURE AND APPLIED CHEMISTRY, 1995, 67 (02) : 249 - 256
12345