Recent developments in transition metal diaryl chemistry

被引：69

作者：

Kays, Deborah L. ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

来源：

DALTON TRANSACTIONS | 2011年 / 40卷 / 04期

基金：

英国工程与自然科学研究理事会;

关键词：

BULKY TERPHENYL LIGANDS; DOPED ZNSE NANOCRYSTALS; JAHN-TELLER DISTORTION; MAIN-GROUP ELEMENTS; HIGH-SPIN IRON(II); CRYSTAL-STRUCTURES; TRIMETHYLSILYLMETHYL COMPOUNDS; ORGANOMETALLIC COMPOUNDS; 2-COORDINATE IRON(II); REDUCTIVE ELIMINATION;

D O I：

10.1039/c0dt01247e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This Perspective discusses the synthesis and reactivity of low-coordinate transition metal diaryl complexes. The development of sterically demanding ligands, in particular m-terphenyls is facilitating the isolation of complexes featuring two-coordinate open-shell transition metal centres. These coordinatively unsaturated complexes are now being investigated for their reaction chemistry, which is not only contributing to the elucidation of the structure and bonding within these systems but is also leading to the formation of novel compounds.

引用

页码：769 / 778

页数：10

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