Electrochemical performance of CoSb3/MWNTs nanocomposite prepared by in situ solvothermal synthesis

被引:31
|
作者
Xie, J [1 ]
Zhao, XB [1 ]
Cao, GS [1 ]
Zhao, MJ [1 ]
机构
[1] Zhejiang Univ, Dept Mat Sci & Engn, Hangzhou 310027, Peoples R China
基金
中国国家自然科学基金;
关键词
nanocomposite; CoSb3; Li-ion batteries; in situ solvothermal synthesis;
D O I
10.1016/j.electacta.2004.11.019
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
In situ solvothermally synthesized composite (SSC) and mechanically blended composite (MBC) of nanosized CoSb3 and multiwalled carbon nanotubes (MWNTs) were prepared and investigated as potential anode materials for Li-ion batteries. It was found that SSC exhibits an entanglement structure of nanosized CoSb3 and MWNTs and shows significantly better cycling stability than MBC. The reversible capacity of SSC electrode reaches 312 mA h g(-1) at the first cycle and remains above 265 mA h g(-1) after 30 cycles. (c) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2725 / 2731
页数:7
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