Effect of salt concentration on poly (vinyl chloride)/poly (acrylonitrile) based hybrid polymer electrolytes

Hybrid, solid polymer electrolyte films consisting of poly (vinyl chloride) (PVC), poly (acrylonitrile) (PAN) and, propylene carbonate (PC) with different concentrations of LiClO4 are prepared by means of a using solvent-casting technique. The structure and complex formation are studied by X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy. The temperature dependence of the ionic conductivities of the polymer films is explained in terms of a free volume model. The conductivities of PVC-PAN-LiClO4-PC complexes are determined at different salt concentrations. The highest ionic conductivity (8.35 x 10(-5) S cm(-1)) is obtained for 8 wt.% LiClO4 in the polyiner complex at 304 K. The thermal stability of the electrolyte is examined by thermogravimetric/differential thermal analysis (TG/DTA). (c) 2007 Elsevier B.V. All rights reserved.