Cadiot-Chodkiewicz active template synthesis of rotaxanes and switchable molecular shuttles with weak intercomponent interactions

被引：93

作者：

Berna, Jose ^{[1
]}

Goldup, Stephen M. ^{[1
]}

Lee, Ai-Lan ^{[1
]}

Leigh, David A. ^{[1
]}

Symes, Mark D. ^{[1
]}

Teobaldi, Gilberto ^{[2
]}

Zerbetto, Francesco ^{[2
]}

机构：

[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

[2] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 23期

关键词：

Cadiot-Chodkiewicz reaction; heterocoupling; molecular shuttles; rotaxanes; template synthesis;

D O I：

10.1002/anie.200800891

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Shuttling fast and loose: Weak interaction, switchable, rotaxane-based molecular shuttles, in which the positional fidelity of the macrocycle is conferred by a single hydrogen bond in each state, are constructed through the high-yielding and selective active template heterocoupling of different functionalized alkynes using the Cadiot-Chodkiewicz reaction. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4392 / 4396

页数：5

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