Tuning of Mn(II)-doped CdS-ZnSsolid solutions for broadband emission

被引：8

作者：

Arora, Sonia ^{[1
]}

Manoharan, S. Sundar ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Mat Chem Lab, Kanpur 208016, Uttar Pradesh, India

来源：

MATERIALS CHEMISTRY AND PHYSICS | 2008年 / 110卷 / 01期

关键词：

photoluminescence; microwave synthesis; quantization; spin-forbidden transitions;

D O I：

10.1016/j.matchemphys.2008.01.007

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Single-phase solid solution of CdxZn1 - yMnyS offers possibility for tuning full color spectrum. A broad emission with FWHM of similar to 155 nm leading to a broadband emission can be harvested in a nominal composition such as Cd0.54Zn0.43Mn0.03S by a compounded effect of CdS, ZnS and ZnS:Mn responsible for blue, green and red emission, respectively. Contribution from (i) quantization of energy levels due to nano-dimension, (ii) emission arising from trap (mid-gap) states and (iii) Mn2+ spin-forbidden T-4(1)->(6)A(1) transition is responsible for the mechanism of PL in these solid solutions. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：34 / 37

页数：4

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