Plasma-Enhanced Copolymerization of Amino Acid and Synthetic Monomers

被引：15

作者：

Anderson, Kyle D. ^{[1
]}

Young, Seth L. ^{[1
]}

Jiang, Hao ^{[2
]}

Jakubiak, Rachel ^{[2
]}

Bunning, Timothy J. ^{[2
]}

Naik, Rajesh R. ^{[2
]}

Tsukruk, Vladimir V. ^{[1
]}

机构：

[1] Georgia Inst Technol, Sch Mat Sci & Engn, Atlanta, GA 30332 USA

[2] USAF, Mat & Mfg Directorate, Res Lab, Wright Patterson AFB, Dayton, OH 45433 USA

来源：

LANGMUIR | 2012年 / 28卷 / 03期

关键词：

CHEMICAL-VAPOR-DEPOSITION; NANOCOMPOSITE THIN-FILMS; POLY(2-HYDROXYETHYL METHACRYLATE); OPTICAL-PROPERTIES; IN-SITU; GROWTH; POLYMERIZATION; SURFACES; BIOCOMPATIBILITY; LUMINESCENT;

D O I：

10.1021/la204416h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this paper we report the use of plasma-enhanced chemical vapor deposition (PECVD) for the simultaneous deposition and copolymerization of an amino acid with other organic and inorganic monomers. We investigate the fundamental effects of plasma-enhanced copolymerization on different material chemistries in stable ultrathin coatings of mixed composition with an amino acid component. This study serves to determine the feasibility of a direct, facile method for integrating biocompatible/active materials into robust polymerized coatings with the ability to plasma copolymerize a biological molecule (L-tyrosine) with different synthetic materials in a dry, one-step process to form ultrathin coatings of mixed composition. This process may lead to a method of interfacing biologic systems with synthetic materials as a way to enhance the biomaterial tissue interface and preserve biological activity within composite films.

引用

页码：1833 / 1845

页数：13

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