Heterometallic complexes with E(6) ligands (E=P,As)

被引：26

作者：

Friedrich, G ^{[1
]}

Scherer, OJ ^{[1
]}

Wolmershauser, G ^{[1
]}

机构：

[1] UNIV KAISERSLAUTERN,FACHBEREICH CHEM,D-67663 KAISERSLAUTERN,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1996年 / 622卷 / 09期

关键词：

trinuclear and tetranuclear P-6 and As-6 complexes; 3xP(2) and 2xAs(3) subunits;

D O I：

10.1002/zaac.19966220908

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of [Cp*Co(mu-CO)](2) 1 with the sandwich complexes [Cp*Fe(eta(5)-E(5))] 2a: E = P, 2b: E = As in decalin at 190 degrees C affords besides [Cp(2)*Co(2)E(4)] 4: E = P, 7: E = As and [Cp(2)*Fe2P4] 5 the trinuclear complexes [(Cp*Fe)(2)(Cp*Co)-(mu-eta(2)-P-2)(mu(3)-eta(1:2:1)-P-2)(2)] 3 as well as [(Cp*Fe)(2)(Cp*Co)(mu(3)-eta(2:2:2)-As-3)(2)] 6. With [Mo(CO)(5)(thf)] 3 and 6 form in a build-up reaction the tetranuclear clusters [(Cp*Fe)(2)(Cp*Co)E(6){Mo(CO)(3)}] 10: E = P, 11: E = As. 3, 6 and 11 have been further characterized by an X-ray crystal structure determination.

引用

页码：1478 / 1486

页数：9

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