New platinum(II) and palladium(II) quinoline-imine-pyridine, quinoline-imine-thiazole and quinoline-imine-imidazole complexes by metal-assisted condensation reactions

被引：13

作者：

Bortoluzzi, Marco ^{[1
]}

Paolucci, Gino ^{[1
]}

Pitteri, Bruno ^{[1
]}

Zennaro, Piero ^{[2
]}

Bertolasi, Valerio ^{[3
,4
]}

机构：

[1] Univ Ca Foscari Venezia, Dipartimento Sci Mol & Nanosistemi, I-30123 Venice, Italy

[2] Univ Ca Foscari Venezia, Dipartimento Sci Ambientali, I-30123 Venice, Italy

[3] Univ Ferrara, Dipartmento Chim, I-44100 Ferrara, Italy

[4] Univ Ferrara, Ctr Strutturist Diffrattometr, I-44100 Ferrara, Italy

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2011年 / 696卷 / 13期

关键词：

Platinum; Palladium; N-Donor ligands; Metal-assisted syntheses; Methyl-complexes; Five-coordinate complexes; SOLVENT-INDUCED AGGREGATION; EFFECTIVE CORE POTENTIALS; SUPRAMOLECULAR RECOGNITION; MOLECULAR RECOGNITION; TERPYRIDINE COMPLEXES; CYTOCHROMES-C; LIGANDS; CRYSTAL; ASSOCIATION; CHEMISTRY;

D O I：

10.1016/j.jorganchem.2011.03.046

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Pt(II) and Pd(II) methyl- and chloro-complexes with the tridentate N-donor ligands ((pyridin-2-yl)methylene)quinolin-8-amine (NNPy), ((pyridin-2-yl)ethylidene)quinolin-8-yl-amine (NNMePy), (phenyl(pyridin-2-yl)methylene)quinolin-8-yl-amine (NNPhPy), ((thiazol-2-yl)methylene)quinolin-8-amine (NNTh) and ((imidazol-4-yl)methylene)quinolin-8-amine (NNImH) were prepared by metal-assisted condensation of 8-aminoquinoline and an ortho-substituted aldehydo- or keto- N-heterocycle. Preliminary reactivity studies involving the coordinated tridentate N-donors, the chloro-ligand and the M-CH3 bond were carried out, leading to the synthesis of several new complexes. During these studies, the formation of a novel five-coordinate Pt(II) carbonyl-complex was observed. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：2565 / 2575

页数：11

共 79 条

[21] Molecular recognition - Allosterism generated by weak host-guest interactions in molecular rectangles [J].

Crowley, JD ;

Steele, IM ;

Bosnich, B .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (19) :3907-3917

[22] Supramolecular recognition forces: An examination of weak metal-metal interactions in host-guest formation [J].

Crowley, JD ;

Steele, IM ;

Bosnich, B .

INORGANIC CHEMISTRY, 2005, 44 (09) :2989-2991

[23] Supramolecular recognition: Protonmotive-driven switches or motors? [J].

Crowley, JD ;

Goshe, AJ ;

Steele, IM ;

Bosnich, B .

CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (08) :1944-1955

[24] Molecular recognition. Electrostatic effects in supramolecular self-assembly [J].

Crowley, JD ;

Goshe, AJ ;

Bosnich, B .

CHEMICAL COMMUNICATIONS, 2003, (03) :392-393

[25] Platinum complexes of terpyridine: Synthesis, structure and reactivity [J].

Cummings, Scott D. .

COORDINATION CHEMISTRY REVIEWS, 2009, 253 (3-4) :449-478

[26] COMPLEXES OF THE PLATINUM METALS CONTAINING WEAK DONOR LIGANDS [J].

DAVIES, JA ;

HARTLEY, FR .

CHEMICAL REVIEWS, 1981, 81 (01) :79-90

[27] NEW NEUTRAL AND IONIC METHYL AND CHLORO PALLADIUM AND PLATINUM COMPLEXES CONTAINING HEMILABILE PHOSPHORUS NITROGEN LIGANDS - STUDY OF THE INSERTION OF CARBON-MONOXIDE INTO THE METAL METHYL BOND [J].

DEKKER, GPCM ;

BUIJS, A ;

ELSEVIER, CJ ;

VRIEZE, K ;

VANLEEUWEN, PWNM ;

SMEETS, WJJ ;

SPEK, AL ;

WANG, YF ;

STAM, CH .

ORGANOMETALLICS, 1992, 11 (05) :1937-1948

[28] TRIFLUOROMETHANESULPHONATO-O COMPLEXES OF PLATINUM(II) AND PALLADIUM(II) [J].

DIVER, C ;

LAWRANCE, GA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (04) :931-934

[29]

Dolg M., 2000, MODERN METHODS ALGOR, VI, P479

[30] THE RESOLUTION OF A BIS-TRIDENTATE IRON(II) COMPLEX [J].

DWYER, FP ;

GILL, NS ;

GYARFAS, EC ;

LIONS, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (15) :3834-3835

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