New platinum(II) and palladium(II) quinoline-imine-pyridine, quinoline-imine-thiazole and quinoline-imine-imidazole complexes by metal-assisted condensation reactions

被引：13
作者：
Bortoluzzi, Marco [1 ]
Paolucci, Gino [1 ]
Pitteri, Bruno [1 ]
Zennaro, Piero [2 ]
Bertolasi, Valerio [3 ,4 ]
机构：
[1] Univ Ca Foscari Venezia, Dipartimento Sci Mol & Nanosistemi, I-30123 Venice, Italy
[2] Univ Ca Foscari Venezia, Dipartimento Sci Ambientali, I-30123 Venice, Italy
[3] Univ Ferrara, Dipartmento Chim, I-44100 Ferrara, Italy
[4] Univ Ferrara, Ctr Strutturist Diffrattometr, I-44100 Ferrara, Italy
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2011年 / 696卷 / 13期
关键词：
Platinum; Palladium; N-Donor ligands; Metal-assisted syntheses; Methyl-complexes; Five-coordinate complexes; SOLVENT-INDUCED AGGREGATION; EFFECTIVE CORE POTENTIALS; SUPRAMOLECULAR RECOGNITION; MOLECULAR RECOGNITION; TERPYRIDINE COMPLEXES; CYTOCHROMES-C; LIGANDS; CRYSTAL; ASSOCIATION; CHEMISTRY;
D O I：
10.1016/j.jorganchem.2011.03.046
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Pt(II) and Pd(II) methyl- and chloro-complexes with the tridentate N-donor ligands ((pyridin-2-yl)methylene)quinolin-8-amine (NNPy), ((pyridin-2-yl)ethylidene)quinolin-8-yl-amine (NNMePy), (phenyl(pyridin-2-yl)methylene)quinolin-8-yl-amine (NNPhPy), ((thiazol-2-yl)methylene)quinolin-8-amine (NNTh) and ((imidazol-4-yl)methylene)quinolin-8-amine (NNImH) were prepared by metal-assisted condensation of 8-aminoquinoline and an ortho-substituted aldehydo- or keto- N-heterocycle. Preliminary reactivity studies involving the coordinated tridentate N-donors, the chloro-ligand and the M-CH3 bond were carried out, leading to the synthesis of several new complexes. During these studies, the formation of a novel five-coordinate Pt(II) carbonyl-complex was observed. (C) 2011 Elsevier B.V. All rights reserved.
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页码：2565 / 2575
页数：11
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