The bifurcation rearrangement in cyclic water clusters: Breaking and making hydrogen bonds

被引：52

作者：

Brown, MG ^{[1
]}

Keutsch, FN ^{[1
]}

Saykally, RJ ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

JOURNAL OF CHEMICAL PHYSICS | 1998年 / 109卷 / 22期

关键词：

D O I：

10.1063/1.477630

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Tunneling patterns observed in the vibration-rotation-tunnelling spectrum of (H2O)(5) measured near 2.7 THz established the time scale:For bifurcation rearrangements to be approximately 40 ns. This relatively local process is likely to be relevant in the dynamics of liquid water and ice. (C) 1998 American Institute of Physics. [S0021-9606(98)02146-1].

引用

页码：9645 / 9647

页数：3

共 25 条

[1] STRUCTURE AND PROPERTIES OF ICE [J].

BJERRUM, N .

SCIENCE, 1952, 115 (2989) :385-390

[2] TEMPERATURE-DEPENDENCE OF DIELECTRIC-RELAXATION IN H2O AND D2O ICE - A DISSIPATIVE QUANTUM TUNNELING APPROACH [J].

BRUNI, F ;

CONSOLINI, G ;

CARERI, G .

JOURNAL OF CHEMICAL PHYSICS, 1993, 99 (01) :538-547

[3] MEASUREMENT OF THE PERPENDICULAR ROTATION-TUNNELING SPECTRUM OF THE WATER DIMER BY TUNABLE FAR INFRARED-LASER SPECTROSCOPY IN A PLANAR SUPERSONIC JET [J].

BUSAROW, KL ;

COHEN, RC ;

BLAKE, GA ;

LAUGHLIN, KB ;

LEE, YT ;

SAYKALLY, RJ .

JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (08) :3937-3943

[4]

CAVATORTA F, 1994, J PHYS CONDENS MATT, V6, P113

[5] HYDROGEN-BOND DYNAMICS IN WATER STUDIED BY DEPOLARIZED RAYLEIGH-SCATTERING [J].

CONDE, O ;

TEIXEIRA, J .

JOURNAL DE PHYSIQUE, 1983, 44 (04) :525-529

[6] DEPOLARIZED LIGHT-SCATTERING OF HEAVY-WATER, AND HYDROGEN-BOND DYNAMICS [J].

CONDE, O ;

TEIXEIRA, J .

MOLECULAR PHYSICS, 1984, 53 (04) :951-959

[7] Quantifying hydrogen bond cooperativity in water: VRT spectroscopy of the water tetramer [J].

Cruzan, JD ;

Braly, LB ;

Liu, K ;

Brown, MG ;

Loeser, JG ;

Saykally, RJ .

SCIENCE, 1996, 271 (5245) :59-62

[8] GROUP THEORETICAL CLASSIFICATION OF TUNNELING-ROTATIONAL ENERGY-LEVELS OF WATER DIMER [J].

DYKE, TR .

JOURNAL OF CHEMICAL PHYSICS, 1977, 66 (02) :492-497

[9] Microwave and submillimeter-wave spectra of the mixed deuterated-protonated water-dimer isotopomers [J].

Fraser, GT ;

Lovas, FJ ;

Suenram, RD ;

Karyakin, EN ;

Grushow, A ;

Burns, WA ;

Leopold, KR .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1997, 181 (02) :229-245

[10] Tunneling dynamics in water tetramer and pentamer [J].

Gregory, JK ;

Clary, DC .

JOURNAL OF CHEMICAL PHYSICS, 1996, 105 (16) :6626-6633

← 1 2 3 →