The bifurcation rearrangement in cyclic water clusters: Breaking and making hydrogen bonds

被引：51
作者：
Brown, MG [1 ]
Keutsch, FN [1 ]
Saykally, RJ [1 ]
机构：
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
来源：
JOURNAL OF CHEMICAL PHYSICS | 1998年 / 109卷 / 22期
关键词：
D O I：
10.1063/1.477630
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Tunneling patterns observed in the vibration-rotation-tunnelling spectrum of (H2O)(5) measured near 2.7 THz established the time scale:For bifurcation rearrangements to be approximately 40 ns. This relatively local process is likely to be relevant in the dynamics of liquid water and ice. (C) 1998 American Institute of Physics. [S0021-9606(98)02146-1].
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收藏
页码：9645 / 9647
页数：3
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