A priori design of new natural deep eutectic solvent for lutein recovery from microalgae

被引：51
作者：
Fan, Chen [1 ]
Liu, Yang [1 ]
Shan, Yuhang [1 ]
Cao, Xueli [1 ]
机构：
[1] Beijing Technol & Business Univ, Beijing Adv Innovat Ctr Food Nutr & Human Hlth, Beijing 100048, Peoples R China
来源：
FOOD CHEMISTRY | 2022年 / 376卷
基金：
北京市自然科学基金;
关键词：
Natural deep eutectic solvent; Microalgae; Lutein; COSMO-RS model; Recovery process; GREEN;
D O I：
10.1016/j.foodchem.2021.131930
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Lutein is an important functional food ingredient. However, its recovery processes developed so far seem to fail in sustainability criteria, regarding the urgent need for improved extraction ability while maintaining stability. This work aimed to study the design and application of natural deep eutectic solvent (NADES) for lutein recovery from Scenedesmus sp with the aid of COSMO-RS. The performance of the novel fenchyl alcohol/thymol-based system was studied comprehensively under different extraction parameters. Furthermore, thermal, light and storage stability of lutein in NADES were investigated. It was found that lutein recovery from microalgae should be performed using equimolar hydrogen-bond acceptor/donor at 60 degrees C within 70 min. The NADES could increase lutein yield compared with the conventional methodology using organic solvents. Besides, it significantly enhanced the lutein stability under various conditions. Hydrogen bond and Van der Waals interaction play crucial roles during target processing, elucidated by theoretical calculations and nuclear magnetic resonance.
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页数：10
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