Syntheses, Crystal Structures, Luminescent and Magnetic Properties of Two 1D Cadmium(II) and Nickel(II) Coordination Polymers

被引：0

作者：

Li Yu ^{[1
]}

Chen Yong-Xuan ^{[1
]}

Zhao Na ^{[1
]}

Feng An-Sheng ^{[1
]}

Zou Xun-Zhong ^{[1
]}

机构：

[1] Guangdong Ind Polytech, Foshan Res Ctr Special Funct Bldg Mat & Its Green, Guangdong Res Ctr Special Bldg Mat & Its Green Pr, Guangzhou 510300, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2020年 / 36卷 / 01期

关键词：

coordination polymer; tetracarboxylic acid; luminescent properties; magnetic properties; NI-II; COMPLEXES; NETWORKS; TOPOLOGY; COBALT;

D O I：

10.11862/CJIC.2020.017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two 1D cadmium(II) and nickel(II) coordination polymers, namely {[M-2(mu(3)-L)(phen)(3)]center dot 5H(2)O}(n) (M=Cd (1), Ni (2)), were constructed hydrothermally using H4L (H4L=3-(2,4-dicarboxyphenyl)-2,6-pyridinedicarboxylic acid), phen (phen=1,10-phenanthroline), and cadmium or nickel chlorides. Single-crystal X-ray diffraction analyses reveal that both compounds are isostructural and crystallize in the orthorhombic system, space group Pbca. Compound 1 or 2 feature a 1D metal-organic chain, which is assembled to a 2D supramolecular network through O-H center dot center dot center dot O hydrogen bond. The luminescent and magnetic properties for two compounds were also investigated.

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页码：192 / 198

页数：7

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共 27 条

[1] Use of liquid-liquid interface (biphasic) for the preparation of benzenetricarboxylate complexes of cobalt and nickel [J].

Banerjee, Abhishek ;

Mahata, Partha ;

Natarajan, Srinivasan .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (22) :3501-3514

[2] Windmill Co4{Co4(μ4-O)} with 16 Divergent Branches Forming a Family of Metal-Organic Frameworks: Organic Metrics Control Topology, Gas Sorption, and Magnetism [J].

Chen, Qing ;

Xue, Wei ;

Lin, Jian-Bin ;

Wei, Yong-Sheng ;

Yin, Zheng ;

Zeng, Ming-Hua ;

Kurmoo, Mohamedally ;

Chen, Xiao-Ming .

CHEMISTRY-A EUROPEAN JOURNAL, 2016, 22 (34) :12088-12094

[3] Luminescent Functional Metal-Organic Frameworks [J].

Cui, Yuanjing ;

Yue, Yanfeng ;

Qian, Guodong ;

Chen, Banglin .

CHEMICAL REVIEWS, 2012, 112 (02) :1126-1162

[4] Thermochromic, Solvatochromic, and Piezochromic Cd(II) and Zn(II) Coordination Polymers: Detection of Small Molecules by Luminescence Switching from Blue to Green [J].

Dey, Avishek ;

Garai, Abhijit ;

Gude, Venkatesh ;

Biradha, Kumar .

CRYSTAL GROWTH & DESIGN, 2018, 18 (10) :6070-6077

[5] First tetrameric NiII cluster with planar triangular topology exhibiting ferromagnetic pathways [J].

Du, M ;

Bu, XH ;

Guo, YM ;

Zhang, L ;

Liao, DZ ;

Ribas, J .

CHEMICAL COMMUNICATIONS, 2002, (14) :1478-1479

[6] Design and construction of coordination polymers with mixed-ligand synthetic strategy [J].

Du, Miao ;

Li, Cheng-Peng ;

Liu, Chun-Sen ;

Fang, Shao-Ming .

COORDINATION CHEMISTRY REVIEWS, 2013, 257 (7-8) :1282-1305

[7] A new series of Cd(ii) metal-organic architectures driven by soft ether-bridged tricarboxylate spacers: synthesis, structural and topological versatility, and photocatalytic properties [J].

Gu, Jin-Zhong ;

Cai, Yan ;

Wen, Min ;

Shi, Zi-Fa ;

Kirillov, Alexander M. .

DALTON TRANSACTIONS, 2018, 47 (40) :14327-14339

[8] A new series of Co, Ni, Zn, and Cd metal-organic architectures driven by an unsymmetrical biphenyl-tricarboxylic acid: hydrothermal assembly, structural features and properties [J].

Gu, Jin-Zhong ;

Cai, Yan ;

Qian, Zi-Yue ;

Wen, Min ;

Shi, Zi-Fa ;

Lv, Dong-Yu ;

Kirillov, Alexander M. .

DALTON TRANSACTIONS, 2018, 47 (22) :7431-7444

[9] Metal-Organic Architectures Assembled from Multifunctional Polycarboxylates: Hydrothermal Self-Assembly, Structures, and Catalytic Activity in Alkane Oxidation [J].

Gu, Jinzhong ;

Wen, Min ;

Cai, Yan ;

Shi, Zifa ;

Arol, Aliaksandr S. ;

Kirillova, Marina V. ;

Kirillov, Alexander M. .

INORGANIC CHEMISTRY, 2019, 58 (04) :2403-2412

[10] Multifunctional Aromatic Carboxylic Acids as Versatile Building Blocks for Hydrothermal Design of Coordination Polymers [J].

Gu, Jinzhong ;

Wen, Min ;

Liang, Xiaoxiao ;

Shi, Zifa ;

Kirillova, Marina V. ;

Kirillov, Alexander M. .

CRYSTALS, 2018, 8 (02)