Laser-flash photolysis of DMSO-Cl complexes in dimethyl sulfoxide/CCl4 mixed solvent

被引：4

作者：

Sumiyoshi, T ^{[1
]}

Minegishi, H ^{[1
]}

Fujiyoshi, R ^{[1
]}

Sawamura, S ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Engn, Div Quantum Energy Engn, Kita Ku, Sapporo, Hokkaido 0608628, Japan

来源：

CHEMISTRY LETTERS | 2005年 / 34卷 / 06期

关键词：

D O I：

10.1246/cl.2005.794

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

DMSO-Cl complexes were produced by pulse radiolysis of mixtures of dimethyl sulfoxide (DMSO) and CCl4 of various compositions, and photochemical reactions were studied by laser flash photolysis. The quantum yields of intramolecular hydrogen abstraction depend strongly on both solvent composition and additives.

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页码：794 / 795

页数：2

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