Lithium salts based on oligoether sulfate esters

被引:14
作者
Chauvin, C
Ollivrin, X
Alloina, F
LeNest, JF
Sanchez, JY
机构
[1] Inst Natl Polytech Grenoble, LEPMI, F-38402 St Martin Dheres, France
[2] Inst Natl Polytech Grenoble, EFPG, F-38402 St Martin Dheres, France
关键词
polymer electrolyte; sulfate salt; ionic conductivity; lithium battery;
D O I
10.1016/j.electacta.2005.02.057
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Salts based on oligoether sulfate have been synthesized. Two families of lithium salt were synthesized, mono and disulfate. The results, in term of ionic conductivities, thermal behaviour, viscosity, transference number and electrochemical stability are reported. These salts have sufficient thermal and electrochemical stabilities and, in addition, they have a cationic transference number close to unity. The influence of alkaline cation was evaluated on conductivity and thermal stability measurements. (c) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3843 / 3852
页数:10
相关论文
共 40 条
  • [1] Comparative ion transport in several polymer electrolytes
    Alloin, F
    Benrabah, D
    Sanchez, JY
    [J]. JOURNAL OF POWER SOURCES, 1997, 68 (02) : 372 - 376
  • [2] ELECTROCHEMICAL-BEHAVIOR OF LITHIUM ELECTROLYTES BASED ON NEW POLYETHER NETWORKS
    ALLOIN, F
    SANCHEZ, JY
    ARMAND, M
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (07) : 1915 - 1920
  • [3] IONIC CONDUCTIVITIES FOR POLY(ETHYLENE OXIDE) COMPLEXES WITH LITHIUM-SALTS OF MONOBASIC AND DIBASIC ACIDS AND BLENDS OF POLY(ETHYLENE OXIDE) WITH LITHIUM-SALTS OF ANIONIC POLYMERS
    BANNISTER, DJ
    DAVIES, GR
    WARD, IM
    MCINTYRE, JE
    [J]. POLYMER, 1984, 25 (09) : 1291 - 1296
  • [4] Bayoudh S, 2000, POLYM INT, V49, P703, DOI 10.1002/1097-0126(200007)49:7<703::AID-PI442>3.0.CO
  • [5] 2-H
  • [6] PERFLUOROSULFONATE-POLYETHER BASED SINGLE-ION CONDUCTORS
    BENRABAH, D
    SYLLA, S
    ALLOIN, F
    SANCHEZ, JY
    ARMAND, M
    [J]. ELECTROCHIMICA ACTA, 1995, 40 (13-14) : 2259 - 2264
  • [7] Carey FA, 1984, ADV ORGANIC CHEM
  • [8] CHAUVIN C, 2004, 9 INT S POL EL POL, P141
  • [9] CHEN H, 1996, PURE APPL CHEM A, V33, P1273
  • [10] CHERADAME H, 1988, BR POLYM J, V20, P253