Nucleation of electroactive β-phase poly(vinilidene fluoride) with CoFe2O4 and NiFe2O4 nanofillers: a new method for the preparation of multiferroic nanocomposites

被引:180
作者
Martins, P. [1 ]
Costa, C. M. [2 ]
Lanceros-Mendez, S. [1 ]
机构
[1] Univ Minho, Ctr Dept Fis, P-4710057 Braga, Portugal
[2] CeNTI Ctr Nanotechnol & Smart Mat, P-4760034 Vila Nova De Famalicao, Portugal
来源
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING | 2011年 / 103卷 / 01期
关键词
POLY(VINYLIDENE FLUORIDE); MAGNETOELECTRIC PROPERTIES; ALPHA-PHASE; CRYSTALLIZATION; TRANSFORMATION;
D O I
10.1007/s00339-010-6003-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Multiferroic and magnetoelectric materials show enormous potential for technological developments. Multiferroic composites are more attractive for applications due to their enhanced properties with respect to single-phase multiferroic materials. In this paper we report on the nucleation of the electroactive beta-phase of poly(vinylidene fluoride), PVDF, by the addition of CoFe2O4 and NiFe2O4 nanoparticles in order to prepare poly(vinylidene fluoride)/ferrite nanocomposite for multiferroic and magnetoelectric applications,. The dispersed ferrite nanofiller particles strongly enhance the nucleation of the beta-phase of the polymer matrix. In this way, magnetoelectric polymer nanocomposites can be processed avoiding the usual alpha- to beta-phase transformation by stretching of the polymer matrix.
引用
收藏
页码:233 / 237
页数:5
相关论文
共 29 条
[1]   Enhanced ferroelectric phase content of polyvinylidene difluoride fibers with the addition of magnetic nanoparticles [J].
Andrew, J. S. ;
Clarke, D. R. .
LANGMUIR, 2008, 24 (16) :8435-8438
[2]   Electrospinning of polyvinylidene difluoride-based nanocomposite fibers [J].
Andrew, J. S. ;
Mack, J. J. ;
Clarke, D. R. .
JOURNAL OF MATERIALS RESEARCH, 2008, 23 (01) :105-114
[3]   Nanocomposites of poly(vinylidene fluoride) with organically modified silicate [J].
Buckley, J ;
Cebe, P ;
Cherdack, D ;
Crawford, J ;
Ince, BS ;
Jenkins, M ;
Pan, JJ ;
Reveley, M ;
Washington, N ;
Wolchover, N .
POLYMER, 2006, 47 (07) :2411-2422
[4]   Giant magnetoelectric coupling and E-field tunability in a laminated Ni2MnGa/lead-magnesium-niobate-lead titanate multiferroic heterostructure [J].
Chen, Yajie ;
Wang, Jingmin ;
Liu, Ming ;
Lou, Jing ;
Sun, Nian X. ;
Vittoria, Carmine ;
Harris, Vincent G. .
APPLIED PHYSICS LETTERS, 2008, 93 (11)
[5]   Magnetic properties and dielectric behavior in ferrite/ferroelectric particulate composites [J].
Devan, R. S. ;
Chougule, B. K. .
PHYSICA B-CONDENSED MATTER, 2007, 393 (1-2) :161-166
[6]   On the structure and morphology of polyvinylidene fluoride-nanoclay nanocomposites [J].
Dillon, DR ;
Tenneti, KK ;
Li, CY ;
Ko, FK ;
Sics, I ;
Hsiao, BS .
POLYMER, 2006, 47 (05) :1678-1688
[7]   Multiferroic and magnetoelectric materials [J].
Eerenstein, W. ;
Mathur, N. D. ;
Scott, J. F. .
NATURE, 2006, 442 (7104) :759-765
[8]   Revival of the magnetoelectric effect [J].
Fiebig, M .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2005, 38 (08) :R123-R152
[9]  
GREGORIO R, 1994, J POLYM SCI POL PHYS, V32, P859, DOI 10.1002/polb.1994.090320509
[10]   EFFECT OF PMMA ADDITION ON THE SOLUTION CRYSTALLIZATION OF THE ALPHA-PHASE AND BETA-PHASE OF POLY(VINYLIDENE FLUORIDE) (PVDF) [J].
GREGORIO, R ;
NOCITI, NCPD .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1995, 28 (02) :432-436