Fabrication of polycrystalline silicon thin films from a-SiOx via the inverted aluminum-induced layer exchange process

被引:13
作者
Zamchiy, A. O. [1 ,2 ]
Baranov, E. A. [1 ]
Maximovskiy, E. A. [2 ,3 ]
Volodin, V. A. [2 ,4 ]
Vdovin, V., I [4 ]
Gutakovskii, A. K. [2 ,4 ]
Korolkov, I., V [2 ,3 ]
机构
[1] Kutateladze Inst Thermophys SB RAS, Ac Lavrentiev Ave 1, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, Pirogova Str 2, Novosibirsk 630090, Russia
[3] Nikolaev Inst Inorgan Chem SB RAS, Ac Lavrentiev Ave 3, Novosibirsk 630090, Russia
[4] Rzhanov Inst Semicond Phys SB RAS, Ac Lavrentiev Ave 13, Novosibirsk 630090, Russia
基金
俄罗斯科学基金会;
关键词
Thin films; Phase transformation; Aluminum-induced crystallization; Inverted aluminum-induced layer exchange; Polycrystalline silicon; Silicon suboxide; INDUCED CRYSTALLIZATION; GROWTH;
D O I
10.1016/j.matlet.2019.127086
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
A novel fabrication method of polycrystalline silicon (poly-Si) films by aluminum-induced crystallization of amorphous silicon suboxide (a-SiO0.2) material via the inverted aluminum-induced layer exchange (ALILE) mechanism on glass substrates is presented. The presence of oxygen in the system prevented the formation of columnar crystalline Si precipitates (hillocks) in the bottom layer of the structure even at a process temperature of 550 degrees C. At the same time, this layer, consisting of Al, Si, and O atoms, contained nanocrystalline Si inclusions and a layer of initial a-SiOx with a thickness of about 60 nm, which was called the "a-SiOx residual layer". The poly-Si formed had a preferred (1 1 1) crystal orientation and an average crystallite size of 4.5 mu m. (C) 2019 Elsevier B.V. All rights reserved.
引用
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页数:4
相关论文
共 25 条
[1]   Structural and optical properties of a-SiOx: H thin films deposited by the GJ EBP CVD method [J].
Baranov, Evgeniy ;
Khmel, Sergey ;
Zamchiy, Alexandr ;
Buyko, Maxim .
PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2016, 213 (07) :1783-1789
[2]   Direct in situ transmission electron microscopy observation of Al push up during early stages of the Al-induced layer exchange [J].
Birajdar, B. I. ;
Antesberger, T. ;
Butz, B. ;
Stutzmann, M. ;
Spiecker, E. .
SCRIPTA MATERIALIA, 2012, 66 (08) :550-553
[3]   Poly-silicon thin films by aluminium induced crystallisation of microcrystalline silicon [J].
Ekanayake, G. ;
Reehal, H. S. .
VACUUM, 2006, 81 (03) :272-278
[4]   Large-grained poly-silicon thin films by aluminium-induced crystallisation of microcrystalline silicon [J].
Ekanayake, G. ;
Quinn, T. ;
Reehal, H. S. .
JOURNAL OF CRYSTAL GROWTH, 2006, 293 (02) :351-358
[5]   Polycrystalline silicon thin-film solar cells on glass [J].
Gall, S. ;
Becker, C. ;
Conrad, E. ;
Dogan, P. ;
Fenske, F. ;
Gorka, B. ;
Lee, K. Y. ;
Rau, B. ;
Ruske, F. ;
Rech, B. .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2009, 93 (6-7) :1004-1008
[6]  
Gall S, 2009, ADV MATER RES-GER, V14, P193
[7]   Two-step crystallization during the reverse aluminum-induced layer exchange process [J].
Jaeger, C. ;
Bator, M. ;
Matich, S. ;
Stutzmann, M. .
JOURNAL OF APPLIED PHYSICS, 2010, 108 (11)
[8]   Controlling Stress in Large-Grained Solid Phase Crystallized n-Type Poly-Si Thin Films To Improve Crystal Quality [J].
Kumar, Avishek ;
Widenborg, Per I. ;
Dalapati, Goutam K. ;
Ke, Cangming ;
Subramanian, Gomathy Sandhya ;
Aberle, Armin .
CRYSTAL GROWTH & DESIGN, 2015, 15 (03) :1067-1072
[9]   Inverted Aluminum-Induced Layer Exchange Method for Thin Film Polycrystalline Silicon Solar Cells on Insulating Substrates [J].
Kuraseko, Hiroshi ;
Orita, Nobuaki ;
Koaizawa, Hisashi ;
Kondo, Michio .
APPLIED PHYSICS EXPRESS, 2009, 2 (01) :0155011-0155013
[10]   Comprehensive study of Al-induced layer-exchange growth for orientation-controlled Si crystals on SiO2 substrates [J].
Kurosawa, Masashi ;
Sadoh, Taizoh ;
Miyao, Masanobu .
JOURNAL OF APPLIED PHYSICS, 2014, 116 (17)