A Rh-catalyzed 1,2-sulfur migration/aza-Diels-Alder cascade initiated by aza-vinyl carbenoids from sulfur-tethered N-sulfonyl-1,2,3-triazoles

被引：55
|
作者：
Jiang, Yu [1 ,2 ]
Tang, Xiang-Ying [3 ]
Shi, Min [1 ,2 ,3 ]
机构：
[1] E China Univ Sci & Technol, Key Lab Adv Mat, Shanghai 200237, Peoples R China
[2] E China Univ Sci & Technol, Inst Fine Chem, Shanghai 200237, Peoples R China
[3] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 11期
基金：
中国国家自然科学基金;
关键词：
RHODIUM(II) AZAVINYL CARBENES; TERMINAL ALKYNES; STEREOCONTROLLED SYNTHESIS; STEREOSELECTIVE-SYNTHESIS; FUSED THIAZOLIDIN-4-ONE; EFFICIENT SYNTHESIS; 2ND SULFENYLATION; TRANSANNULATION; REACTIVITY; PYRROLES;
D O I：
10.1039/c4cc08829h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel Rh(II) catalyzed intramolecular 1,2-sulfur rearrangement/inter-molecular aza-Diels-Alder cascade initiated by azavinyl carbenes has been developed, efficiently affording sulfur-containing tetrahydropyridine derivatives or a, b-unsaturated imines with a broad substrate scope.
引用
收藏
页码：2122 / 2125
页数：4
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