Liquid Organic Frameworks: The Single-Network "Plumber's Nightmare" Bicontinuous Cubic Liquid Crystal

被引：33
|
作者：
Poppe, Silvio [3 ]
Cheng, Xiaohong [3 ,4 ]
Chen, Changlong [1 ]
Zeng, Xiangbing [2 ]
Zhang, Rui-bin [2 ]
Liu, Feng [1 ]
Ungar, Goran [1 ,2 ]
Tschierske, Carsten [3 ]
机构：
[1] Xi An Jiao Tong Univ, Shaanxi Int Res Ctr Soft Matter, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China
[2] Univ Sheffield, Dept Mat Sci & Engn, Sheffield S1 3JD, S Yorkshire, England
[3] Martin Luther Univ Halle Wittenberg, Inst Chem, D-06120 Halle, Germany
[4] Yunnan Univ, Key Lab Med Chem Nat Resources, Chem Dept, Kunming 650091, Yunnan, Peoples R China
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2020年 / 142卷 / 07期
基金：
中国国家自然科学基金; 英国工程与自然科学研究理事会;
关键词：
PHASE;
D O I：
10.1021/jacs.9b11073
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Novel bolapolyphiles, built of a p-terphenyl or bistolane core with polar glycerol end-groups and two laterally attached n-alkyl or semiperfluoroalkyl chains, form the first "single plumber's nightmare network", the simplest soft-matter cubic phase (Pm (3) over barm). Its cage-like grid comprises bundles of aromatic rods lying along the cubic unit cell edges, connected by six-way hydrogen-bonded junctions. Side-chains fill the remaining volume of this unique noninterpenetrating liquid-crystalline organic framework.
引用
收藏
页码：3296 / 3300
页数：5
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