Ultra-small CoO nanocrystals anchored on reduced graphene oxide for enhanced lithium storage in lithium ion batteries

被引:13
作者
Bindumadhavan, Kartick [1 ]
Chang, Pei-Yi [1 ]
Yeh, Ming-Hsiu [2 ]
Doong, Ruey-an [1 ,2 ]
机构
[1] Natl Chiao Tung Univ, Inst Environm Engn, 1001 Univ Rd, Hsinchu 30010, Taiwan
[2] Natl Tsing Hua Univ, Dept Biomed Engn & Environm Sci, 101,Sec 2,Kuang Fu Rd, Hsinchu 30013, Taiwan
关键词
ANODE MATERIAL; CARBON; PERFORMANCE; NANOSHEETS; CAPACITY; NANOSTRUCTURES; NANOPARTICLES; NANOHYBRIDS; COMPOSITE; ELECTRODE;
D O I
10.1557/mrc.2017.30
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this study, we have developed a facile and simple route for preparation of ultrafine CoO/reduced graphene oxide (rGO) nanohybrids with tunable particle size and crystallinity for lithium-ion battery ( LIB) application. At the optimized calcination time of 60 min, the homogeneous and ultrafine CoO nanoparticles with mean size of 4.5 nm can be intimately attached onto rGO surface to rapidly transport Li ions and electrons. The CoO/rGO exhibits excellent rate capability and high specific capacity of 520 mAh/g at 2400 mA/g. In addition, the capacity can be recovered to 900 mAh/g at 150 mA/g after 60 cycles, indicating the superior electrochemical performance of CoO/rGO for LIB applications.
引用
收藏
页码:236 / 244
页数:9
相关论文
共 35 条
[1]   Ultrafine CoO Embedded Reduced Graphene Oxide Nanocomposites: A High Rate Anode for Li-Ion Battery [J].
Bindumadhavan, Kartick ;
Yeh, Ming-Hsiu ;
Chou, Tsu-Chin ;
Chang, Pei-Yi ;
Doong, Rueyan .
CHEMISTRYSELECT, 2016, 1 (18) :5758-5767
[2]   Size Effect of Ordered Mesoporous Carbon Nanospheres for Anodes in Li-Ion Battery [J].
Chang, Pei-Yi ;
Bindumadhavan, Kartick ;
Doong, Ruey-An .
NANOMATERIALS, 2015, 5 (04) :2348-2358
[3]   Chemical-free synthesis of graphene-carbon nanotube hybrid materials for reversible lithium storage in lithium-ion batteries [J].
Chen, Shuangqiang ;
Yeoh, Waikong ;
Liu, Qi ;
Wang, Guoxiu .
CARBON, 2012, 50 (12) :4557-4565
[4]   Rational design of metal oxide hollow nanostructures decorated carbon nanosheets for superior lithium storage [J].
Dong, Yanfeng ;
Liu, Shaohong ;
Liu, Yang ;
Tang, Yongchao ;
Yang, Ting ;
Wang, Xuzhen ;
Wang, Zhiyu ;
Zhao, Zongbin ;
Qiu, Jieshan .
JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (45) :17718-17725
[5]   A Top-Down Strategy toward 3D Carbon Nanosheet Frameworks Decorated with Hollow Nanostructures for Superior Lithium Storage [J].
Dong, Yanfeng ;
Yu, Mingliang ;
Wang, Zhiyu ;
Liu, Yang ;
Wang, Xuzhen ;
Zhao, Zongbin ;
Qiu, Jieshan .
ADVANCED FUNCTIONAL MATERIALS, 2016, 26 (42) :7590-7598
[6]   Compressible graphene aerogel supported CoO nanostructures as a binder-free electrode for high-performance lithium-ion batteries [J].
Dong, Yanfeng ;
Liu, Shaohong ;
Wang, Zhiyu ;
Liu, Yang ;
Zhao, Zongbin ;
Qiu, Jieshan .
RSC ADVANCES, 2015, 5 (12) :8929-8932
[7]   Challenges in the development of advanced Li-ion batteries: a review [J].
Etacheri, Vinodkumar ;
Marom, Rotem ;
Elazari, Ran ;
Salitra, Gregory ;
Aurbach, Doron .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (09) :3243-3262
[8]   Synthesis of CoO/Reduced Graphene Oxide Composite as an Alternative Additive for the Nickel Electrode in Alkaline Secondary Batteries [J].
Fu, Gaoliang ;
Chang, Kun ;
Shangguan, Enbo ;
Tang, Hongwei ;
Li, Bao ;
Chang, Zhaorong ;
Yuan, Xiao-Zi ;
Wang, Haijiang .
ELECTROCHIMICA ACTA, 2015, 180 :373-381
[9]   CoO octahedral nanocages for high-performance lithium ion batteries [J].
Guan, Hasigaowa ;
Wang, Xi ;
Li, Huiqiao ;
Zhi, Chunyi ;
Zhai, Tianyou ;
Bando, Yoshio ;
Golberg, Dmitri .
CHEMICAL COMMUNICATIONS, 2012, 48 (40) :4878-4880
[10]   Low Temperature Vacuum Synthesis of Triangular CoO Nanocrystal/Graphene Nanosheets Composites with Enhanced Lithium Storage Capacity [J].
Guan, Qun ;
Cheng, Jianli ;
Li, Xiaodong ;
Wang, Bin ;
Huang, Ling ;
Nie, Fude ;
Ni, Wei .
SCIENTIFIC REPORTS, 2015, 5