Surface characterization and reactivity of Pd8Ni92 (111) and (110) alloys

被引：61

作者：

Michel, AC ^{[1
]}

Lianos, L ^{[1
]}

Rousset, JL ^{[1
]}

Delichere, P ^{[1
]}

Prakash, NS ^{[1
]}

Massardier, J ^{[1
]}

Jugnet, Y ^{[1
]}

Bertolini, JC ^{[1
]}

机构：

[1] Inst Rech Catalyse, CNRS, F-69626 Villeurbanne, France

来源：

SURFACE SCIENCE | 1998年 / 416卷 / 1-2期

关键词：

butadiene hydrogenation; catalysis; LEIS; low index single crystal surfaces; palladium-nickel; XPS;

D O I：

10.1016/S0039-6028(98)00614-1

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Pd8Ni92 (111) and (110) surfaces have been investigated using X-ray photoelectron spectroscopy and low energy ion scattering. As expected, a high rate of Pd segregation is observed on both faces leading to Fd surface concentrations of 76 and 81 at.% on the (111) and (110) surfaces, respectively. The catalytic performances of these surfaces have been studied for the 1,3-butadiene hydrogenation reaction. The catalytic activity of these alloys is greatly enhanced relative to that of the pure Fd(lll) and (110) surfaces. (C) 1998 Published by Elsevier Science B.V. All rights reserved.

引用

页码：288 / 294

页数：7

共 50 条

[21] UNOCCUPIED BULK, SURFACE, AND IMAGE STATES ON NI(001), NI(111), AND NI(110)
GARRETT, RF
SMITH, NV
PHYSICAL REVIEW B, 1986, 33 (06): : 3740 - 3744
[22] SURFACE EXAFS AND XANES STUDIES OF S/NI(110) AND S/NI(111)
OHTA, T
KITAJIMA, Y
STEFAN, PM
STEFAN, MLS
KOSUGI, N
KURODA, H
JOURNAL DE PHYSIQUE, 1986, 47 (C-8): : 503 - 508
[23] Surface ternary alloys of(Cu,Au)/Ni(110)
Mosca, HO
Garcés, JE
Bozzolo, GH
SURFACE SCIENCE, 2000, 454 (01) : 707 - 711
[24] PREPARATION AND OXIDATION OF NI(111)-FE SURFACE ALLOYS
VREEBURG, RJ
GIJZEMAN, OLJ
GEUS, JW
SURFACE SCIENCE, 1991, 245 (1-2) : 111 - 124
[25] The interaction of CO with Ni(111)-Fe surface alloys
Vreeburg, R. J.
van de Loosdrecht, J.
Gijzeman, O. L. J.
Geus, J. W.
CATALYSIS TODAY, 1991, 10 (03) : 329 - 336
[26] THE ADSORPTION OF N2 - CHEMISORBED ON NI(110) AND PHYSISORBED ON PD(111)
HORN, K
DINARDO, J
EBERHARDT, W
FREUND, HJ
PLUMMER, EW
SURFACE SCIENCE, 1982, 118 (03) : 465 - 495
[27] PHENOL ON NI(110) - CHARACTERIZATION OF SURFACE PHENOXIDE
STEINMULLER, D
RAMSEY, MG
NETZER, FP
NEUBER, M
SURFACE SCIENCE, 1992, 271 (03) : 567 - 574
[28] Water dissociation on Ni(100) and Ni(111): Effect of surface temperature on reactivity
Seenivasan, H.
Tiwari, Ashwani K.
JOURNAL OF CHEMICAL PHYSICS, 2013, 139 (17):
[29] SURFACE SEGREGATION IN ALLOYS - EQUILIBRIUM SEGREGATION OF AU TO (111) SURFACE OF NI
BURTON, JJ
HELMS, CR
POLIZZOTTI, RS
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY, 1976, 13 (01): : 204 - 208
[30] Surface electronic structure of Pt(110): comparison with Ni and Pd
Memmel, N
Rangelov, G
Bertel, E
PROGRESS IN SURFACE SCIENCE, 2003, 74 (1-8) : 239 - 249

← 1 2 3 4 5 →